{"id":"W1752177536","doi":"10.1002/zaac.201400491","title":"Synthesis, Spectroscopic and Molecular Studies of Half‐Sandwich η<sup>6</sup>‐Arene Ruthenium, Cp* Rhodium and Cp* Iridium Metal Complexes with Bidentate Ligands","year":2015,"lang":"en","type":"article","venue":"Zeitschrift für anorganische und allgemeine Chemie","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Denticity; Iridium; Medicinal chemistry; Ruthenium; Rhodium; Ligand (biochemistry); Amine gas treating; Cationic polymerization; Phosphine; Chelation; Benzene; Metal; Stereochemistry; Polymer chemistry; Inorganic chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001862151,0.000206088,0.0001893894,0.00009178981,0.0001170774,0.0002060123,0.0003198729,0.0002258404,0.0008990706],"category_scores_gemma":[0.0002299625,0.0001370505,0.0001136783,0.0001039868,0.0001440549,0.0001593378,0.0001245863,0.000280389,0.0002986552],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002521156,"about_ca_system_score_gemma":0.00007215189,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000654116,"about_ca_topic_score_gemma":0.000411896,"domain_scores_codex":[0.9999131,0.00001829091,0.000004902434,0.00001884989,0.00002711509,0.00001778926],"domain_scores_gemma":[0.9998822,0.00001957206,0.00004034352,0.00001177189,0.00002789806,0.00001825828],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006357406,0.00001217203,0.00006745876,0.00003420391,0.000004699454,0.00002126384,0.00001874073,0.0001190803,0.9988337,0.000111903,0.00003206548,0.0006812298],"study_design_scores_gemma":[0.000009196988,0.0001008361,0.000715551,0.000001771526,0.000005961881,0.00006821939,0.0000100681,0.0008067564,0.9974316,0.000009364743,0.0008366689,0.000004138715],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9963051,0.0005604367,0.001746605,0.00004190336,0.000007409797,0.00001344061,0.00007833709,0.00005114681,0.001195686],"genre_scores_gemma":[0.9960225,0.0002838491,0.001937256,0.00002009633,0.000004494194,0.00001619239,0.0001160183,0.00001352316,0.001586105],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008990706,"threshold_uncertainty_score":0.00300771,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02210802951099539,"score_gpt":0.2748154227003261,"score_spread":0.2527073931893307,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}