{"id":"W1770302995","doi":"10.1039/c5qo00154d","title":"The remarkable role of solvent in reaction mechanism studies by electrospray mass spectrometry","year":2015,"lang":"en","type":"article","venue":"Organic Chemistry Frontiers","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"IONICS Mass Spectrometry (Canada)","funders":"Youth Innovation Promotion Association; Youth Innovation Promotion Association of the Chinese Academy of Sciences; National Natural Science Foundation of China","keywords":"Chemistry; Electrospray mass spectrometry; Electrospray; Mass spectrometry; Solvent; Mechanism (biology); Chromatography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.002022034,0.001116387,0.0007051559,0.0008223245,0.0003097051,0.000750712,0.0009867596,0.0007587972,0.0008093918],"category_scores_gemma":[0.001645351,0.0003289896,0.0004768982,0.0005302277,0.0008810943,0.001766762,0.0005618224,0.001311443,0.000417275],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003504825,"about_ca_system_score_gemma":0.0004045843,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002037189,"about_ca_topic_score_gemma":0.0002337127,"domain_scores_codex":[0.9992866,0.0002254931,0.00005267748,0.0001730021,0.0002155692,0.00004670127],"domain_scores_gemma":[0.9990596,0.0006495076,0.00006731667,0.00006097618,0.0001326093,0.00003009867],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002219735,0.00007496206,0.0005018525,0.001768227,0.0000620373,0.0005370833,0.0001563807,0.0008701152,0.9323177,0.009039383,0.0004843218,0.05396599],"study_design_scores_gemma":[0.00002040643,0.0004139259,0.0004691598,0.00006738344,0.00005042731,0.0005944298,0.00004501218,0.002092273,0.9800776,0.003189067,0.01293829,0.00004189867],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.2623028,0.2105446,0.5066547,0.001526032,0.001115176,0.0004390059,0.0003626148,0.001070325,0.0159847],"genre_scores_gemma":[0.6124836,0.1779848,0.2002955,0.0008675017,0.0008204471,0.0003086693,0.0003996593,0.0002580301,0.006581752],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.002022034,"threshold_uncertainty_score":0.01069361,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007520531479716005,"score_gpt":0.2308942903619163,"score_spread":0.2233737588822003,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}