{"id":"W1772284490","doi":"10.1039/c5nj01756d","title":"Synthesis and structure of a new phosphonium-1-indenylide (PHIN) ligand, 4,7-dimethyl-1-C<sub>9</sub>H<sub>4</sub>PMePh<sub>2</sub>, and of new PHIN complexes of rhodium and iridium","year":2015,"lang":"en","type":"article","venue":"New Journal of Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Winnipeg; University of Manitoba; Queen's University","funders":"","keywords":"Chemistry; Rhodium; Phosphonium; Ligand (biochemistry); Iridium; Stereochemistry; X-ray crystallography; Crystallography; Catalysis; Diffraction; Physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009077106,0.0002274639,0.0001780698,0.0001402038,0.0003058159,0.0002035673,0.0007139651,0.0002650862,0.003275194],"category_scores_gemma":[0.0001093415,0.0001663024,0.0001174723,0.0001474963,0.0001706076,0.0003701235,0.0002994827,0.0005489666,0.000935856],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005571473,"about_ca_system_score_gemma":0.0004493298,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009766984,"about_ca_topic_score_gemma":0.001678447,"domain_scores_codex":[0.999949,0.000005795801,0.000003255676,0.00001591911,0.00001571901,0.00001039103],"domain_scores_gemma":[0.9999501,0.000005528431,0.00001070694,0.00001070851,0.000007934117,0.00001500964],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003026492,0.00006971295,0.0002062835,0.0003475285,0.00001006857,0.0001840402,0.00009371709,0.0009118933,0.9769101,0.002939907,0.0004952762,0.01752883],"study_design_scores_gemma":[0.00002633165,0.0002606152,0.0005387882,0.000008615872,0.000009713282,0.0003180888,0.00002042346,0.0007014945,0.9768833,0.0001515514,0.02106833,0.00001289901],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9269839,0.004533451,0.03312877,0.0004893755,0.0001190507,0.0003756662,0.001447325,0.0005437332,0.03237891],"genre_scores_gemma":[0.9314776,0.002330244,0.03615552,0.0001881327,0.00002172482,0.0002416947,0.001496487,0.00009518523,0.02799326],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003275194,"threshold_uncertainty_score":0.01095659,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01441224427646387,"score_gpt":0.218934984276655,"score_spread":0.2045227400001911,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}