{"id":"W1779146139","doi":"10.1039/c5cc05114b","title":"First homoleptic MIC and heteroleptic NHC–MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligands","year":2015,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":82,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University; Regional Municipality of Waterloo","funders":"","keywords":"Homoleptic; Tris; Chemistry; Ligand (biochemistry); Polymer chemistry; Stereochemistry; Crystallography; Medicinal chemistry; Organic chemistry; Metal; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008176394,0.0002028515,0.0002312922,0.0001391357,0.0002550755,0.0003401291,0.0004247068,0.0002445485,0.001238975],"category_scores_gemma":[0.0001507629,0.0001855418,0.0001213646,0.0001090033,0.0002711197,0.0002373323,0.0004309342,0.0002860108,0.0003728139],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003329069,"about_ca_system_score_gemma":0.0002634306,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006657162,"about_ca_topic_score_gemma":0.001781597,"domain_scores_codex":[0.9999006,0.00001194136,0.000006545713,0.00001994066,0.00002437403,0.00003665786],"domain_scores_gemma":[0.9999249,0.000008852014,0.00001195534,0.00001410192,0.00001342241,0.00002678576],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000208526,0.00002224093,0.0002570419,0.0001864005,0.000009537366,0.0001701805,0.00009933843,0.0005620854,0.9907968,0.002193934,0.0004796233,0.005014323],"study_design_scores_gemma":[0.00002088824,0.0002462214,0.001796704,0.00001170333,0.00001096454,0.0002419154,0.00005231993,0.001592345,0.9902585,0.0002140848,0.005534614,0.00001972125],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9873448,0.0008728077,0.003735983,0.00006894649,0.00002832326,0.00004478782,0.0003181536,0.0002745327,0.007311635],"genre_scores_gemma":[0.993552,0.0002422966,0.003446114,0.0000291544,0.000004526143,0.00003669407,0.0003859142,0.00005532892,0.002248046],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001238975,"threshold_uncertainty_score":0.004144788,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03391508891937795,"score_gpt":0.2588165571214149,"score_spread":0.2249014682020369,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}