{"id":"W1782904988","doi":"10.1002/jgrd.50783","title":"Heterogeneous formation of nitryl chloride and its role as a nocturnal NO<i><sub>x</sub></i> reservoir species during CalNex‐LA 2010","year":2013,"lang":"en","type":"article","venue":"Journal of Geophysical Research Atmospheres","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":110,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland; University of Calgary","funders":"","keywords":"Chemistry; Aerosol; Sunrise; Chloride; Alkyl; Halogen; Analytical Chemistry (journal); Environmental chemistry; Meteorology; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005709623,0.0002019199,0.0003947603,0.00001118897,0.0002759241,0.0002056342,0.0004422484,0.0001294112,0.001250436],"category_scores_gemma":[0.0007747577,0.0001508536,0.0001700947,0.0003177443,0.0003003887,0.0009821726,0.00008850251,0.0008800318,0.0002799307],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002063114,"about_ca_system_score_gemma":0.0001577507,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007830976,"about_ca_topic_score_gemma":0.0001137799,"domain_scores_codex":[0.9972068,0.0002010405,0.0005925495,0.0002102707,0.001213375,0.0005759733],"domain_scores_gemma":[0.9974261,0.0007833196,0.0003376607,0.0001874504,0.0007735119,0.0004919873],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001131731,0.0001482046,0.008049877,0.0002819773,0.0001027138,0.0001862857,0.0004040921,0.001629227,0.9804729,0.00002192391,0.001757275,0.005813775],"study_design_scores_gemma":[0.0007846712,0.0007839339,0.1227623,0.0002219257,0.00001749964,0.0003988906,0.000571054,0.004039824,0.866901,0.002595039,0.0007006626,0.0002232526],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960154,0.0008781549,0.000008993647,0.0002105476,0.0001033212,0.0001739525,0.00001445201,0.000009197527,0.002585933],"genre_scores_gemma":[0.9977121,0.0006034345,0.0002469296,0.00002216457,0.0006225524,0.000002357456,0.000004499162,0.000009099578,0.0007768077],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1147124,"threshold_uncertainty_score":0.9996626,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.017570982343601,"score_gpt":0.2453776319305202,"score_spread":0.2278066495869192,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}