{"id":"W1785442443","doi":"10.1149/1.1480014","title":"Understanding the Anomalous Capacity of Li/Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] Cells Using In Situ X-Ray Diffraction and Electrochemical Studies","year":2002,"lang":"en","type":"article","venue":"Journal of The Electrochemical Society","topic":"Advancements in Battery Materials","field":"Engineering","cited_by":995,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Dalhousie University","keywords":"Electrochemistry; Lithium (medication); Stoichiometry; Oxygen; Formula unit; Diffraction; X-ray crystallography; Plateau (mathematics); Analytical Chemistry (journal); Oxidation state; Crystallography; Chemistry; Materials science; Electrode; Metal; Crystal structure; Physical chemistry; Physics; Metallurgy","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0006005854,0.0003809981,0.0006711525,0.00005922859,0.0002055102,0.00005617761,0.000411204,0.0002469831,0.000009309449],"category_scores_gemma":[0.0001650311,0.0002685956,0.0002722864,0.0004047567,0.0003134081,0.0003216304,0.0001343507,0.001096492,0.000001386404],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001574703,"about_ca_system_score_gemma":0.0000264516,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001402728,"about_ca_topic_score_gemma":0.000003203819,"domain_scores_codex":[0.997552,0.0001314253,0.0009071491,0.0002553896,0.0004925442,0.0006614554],"domain_scores_gemma":[0.9985963,0.0003825199,0.0005270564,0.0002822055,0.0001156965,0.00009619854],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004764697,0.00009207782,0.0002221232,0.0001282155,0.0003044755,0.000001897718,0.001202235,0.0004194583,0.9966399,0.000010596,0.0008706306,0.0000607462],"study_design_scores_gemma":[0.0006901803,0.00008613292,0.0002464134,0.0002107968,0.0001475114,0.000108608,0.0004356966,0.002653742,0.9934283,0.001673459,0.00004149148,0.0002776764],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9786195,0.001884106,0.0184571,0.0002785372,0.0004197804,0.00027813,0.000003969614,0.00003477574,0.00002410877],"genre_scores_gemma":[0.9959359,0.002213617,0.001233415,0.0001785897,0.0003684402,0.000007806436,9.480719e-7,0.00005529726,0.000006033093],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01731637,"threshold_uncertainty_score":0.9999766,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0415174191667518,"score_gpt":0.2444073684948784,"score_spread":0.2028899493281266,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}