{"id":"W1791356206","doi":"10.1039/c5cy00267b","title":"Sulfonic acid-functionalized periodic mesoporous organosilicas in esterification and selective acylation reactions","year":2015,"lang":"en","type":"article","venue":"Catalysis Science & Technology","topic":"Mesoporous Materials and Catalysis","field":"Materials Science","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Acylation; Catalysis; Mesoporous organosilica; Sulfonic acid; Chemistry; Mesoporous material; Solid acid; Organic chemistry; Combinatorial chemistry; Mesoporous silica","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001634603,0.0002392156,0.0001549385,0.0001749804,0.0001239367,0.0001911171,0.0001527348,0.0002768375,0.000820186],"category_scores_gemma":[0.0001091344,0.0002355595,0.0001481063,0.0001425941,0.0001762514,0.0002895264,0.00013716,0.0001953485,0.0004125465],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001407567,"about_ca_system_score_gemma":0.0001342705,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003069478,"about_ca_topic_score_gemma":0.0009515102,"domain_scores_codex":[0.9999315,0.0000108814,0.000007564592,0.00001144498,0.00001938577,0.00001929692],"domain_scores_gemma":[0.9999621,0.000008854893,0.000008887159,0.000004377232,0.000005440964,0.00001028746],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001103722,0.00001370388,0.00008300452,0.00004030234,0.00000554326,0.00006111655,0.00001340564,0.0002626271,0.9970504,0.0003788454,0.00005302737,0.001927584],"study_design_scores_gemma":[0.0000106859,0.0001452647,0.0004411516,0.000002671783,0.00001042848,0.00006268155,0.000007432753,0.0009868209,0.9971622,0.00004883083,0.001116848,0.00000501565],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9936005,0.001194739,0.002041237,0.00004666487,0.00003949925,0.00001376819,0.00006769888,0.00006431405,0.002931604],"genre_scores_gemma":[0.9955094,0.0007106474,0.001823173,0.00001941135,0.00001377262,0.000008634377,0.0000830411,0.000009017667,0.001822808],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000820186,"threshold_uncertainty_score":0.002743781,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0180600390667742,"score_gpt":0.2632209792280388,"score_spread":0.2451609401612646,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}