{"id":"W1791415390","doi":"10.1002/jms.3448","title":"Direct targeted glycation of the free sulfhydryl group of cysteine residue (Cys‐34) of BSA. Mapping of the glycation sites of the anti‐tumor Thomsen–Friedenreich neoglycoconjugate vaccine prepared by Michael addition reaction","year":2014,"lang":"en","type":"article","venue":"Journal of Mass Spectrometry","topic":"Glycosylation and Glycoproteins Research","field":"Biochemistry, Genetics and Molecular Biology","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Fisheries and Oceans Canada; Université du Québec à Montréal; Health Sciences Centre; Memorial University of Newfoundland","funders":"","keywords":"Chemistry; Glycation; Glycoconjugate; Mass spectrometry; Electrospray ionization; Chromatography; Dehydroalanine; Glycan; Matrix-assisted laser desorption/ionization; Peptide; Biochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001123988,0.0003757661,0.0001659258,0.0001257268,0.0000874773,0.0001171907,0.0001359186,0.0002348981,0.0005927984],"category_scores_gemma":[0.0001608574,0.00009886704,0.0002052841,0.00009491644,0.0001798112,0.0001143437,0.0001852743,0.0003417105,0.0001965781],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002058798,"about_ca_system_score_gemma":0.0001323308,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003689,"about_ca_topic_score_gemma":0.0004473118,"domain_scores_codex":[0.9999131,0.00001568481,0.000003798592,0.00002105178,0.00002554459,0.00002080799],"domain_scores_gemma":[0.9999077,0.00001726398,0.00003761028,0.00000890191,0.000013394,0.00001501756],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002749649,0.000003690741,0.00007991528,0.00001219661,0.000002430574,0.00001216951,0.000006712035,0.00002683708,0.9994597,0.0000157469,0.000004163009,0.000349047],"study_design_scores_gemma":[0.000002430272,0.0001249153,0.001377458,0.000001192939,0.000007184484,0.00008241078,0.000005044687,0.0002695927,0.9976426,0.00001419592,0.0004712286,0.000001782194],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9935945,0.0004666158,0.005315346,0.00003563463,0.000009027073,0.00002086898,0.0001103892,0.00003300902,0.0004147145],"genre_scores_gemma":[0.9931201,0.0005741626,0.004850019,0.00003121794,0.000006912188,0.00001813614,0.0002061509,0.00001298512,0.001180489],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005927984,"threshold_uncertainty_score":0.001983106,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006007950796344665,"score_gpt":0.2239891327265819,"score_spread":0.2179811819302372,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}