{"id":"W1796685376","doi":"10.1021/om001067y","title":"Organometallic Oxides:  Oxidation of the Cubane [(η-C<sub>5</sub>R<sub>5</sub>)Cr(μ<sub>3</sub>-O)]<sub>4</sub> and the Structures and Magnetic Properties of the Salts {[(η-C<sub>5</sub>R<sub>5</sub>)Cr(μ<sub>3</sub>-O)]<sub>4</sub>}{tcnq} and {[(η-C<sub>5</sub>R<sub>5</sub>)Cr(μ<sub>3</sub>-O)]<sub>4</sub>}{BF<sub>4</sub>}","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia; University of New Brunswick","funders":"","keywords":"Cubane; Chemistry; Antiferromagnetism; Crystallography; Differential pulse voltammetry; Chromium; Unpaired electron; Cyclic voltammetry; Crystal structure; Molecule; Electrochemistry; Physical chemistry; Condensed matter physics; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","open_science","research_integrity"],"category_scores_codex":[0.0183344,0.02049172,0.01957218,0.01107187,0.01244543,0.009907614,0.01850157,0.01070528,0.0006495854],"category_scores_gemma":[0.01137099,0.01889968,0.008207591,0.02486777,0.02207917,0.01304021,0.0149631,0.01482043,0.003487966],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.006761375,"about_ca_system_score_gemma":0.007993774,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005252998,"about_ca_topic_score_gemma":0.007843778,"domain_scores_codex":[0.9063549,0.01324915,0.02207054,0.02067336,0.01880058,0.01885145],"domain_scores_gemma":[0.9333233,0.00898717,0.01914206,0.01984771,0.009831862,0.008867963],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.005600093,0.005012782,0.002577582,0.006034911,0.004016102,0.0009586951,0.006509525,0.001977364,0.8527467,0.002386751,0.007178378,0.1050011],"study_design_scores_gemma":[0.02164178,0.004233203,0.03167597,0.004378138,0.008559387,0.004341688,0.004161518,0.003867963,0.8874364,0.008925294,0.002612687,0.01816593],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9295667,0.015506,0.002009917,0.00560065,0.01120257,0.02426783,0.005932983,0.004990994,0.0009223716],"genre_scores_gemma":[0.9253702,0.04781628,0.0009358071,0.004977854,0.006025483,0.005367447,0.003330143,0.006077605,0.00009920816],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0868352,"threshold_uncertainty_score":0.99763,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01303303765685982,"score_gpt":0.2021096045773092,"score_spread":0.1890765669204494,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}