{"id":"W1823863301","doi":"10.1039/c5cc04484g","title":"H-phosphonate-mediated sulfonylation of heteroaromatic N-oxides: a mild and metal-free one-pot synthesis of 2-sulfonyl quinolines/pyridines","year":2015,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":119,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Sulfonyl; Phosphonate; Chemistry; Metal; Combinatorial chemistry; Medicinal chemistry; Organic chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003697292,0.0002662381,0.0006435504,0.000148159,0.00006107032,0.0000179843,0.001633437,0.0002756223,0.00005094045],"category_scores_gemma":[0.005603766,0.0002724643,0.0001577973,0.0003757771,0.0007292392,0.0001730892,0.000735197,0.0002689145,0.000006708111],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001015672,"about_ca_system_score_gemma":0.0001071157,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002513748,"about_ca_topic_score_gemma":0.00002642796,"domain_scores_codex":[0.9980506,0.0001013216,0.0009338807,0.0002911908,0.0003861439,0.0002368366],"domain_scores_gemma":[0.9933388,0.002408343,0.0005294037,0.003129199,0.0004175903,0.000176669],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005466565,0.0004439577,0.001139904,0.0002665839,0.000116102,2.679167e-7,0.0002934213,0.000001183649,0.9958941,0.0003882156,0.0003503252,0.001051231],"study_design_scores_gemma":[0.0004945514,0.00001933504,0.0002325002,0.0003708556,0.0001827178,0.000004555065,0.0003106627,0.0007275195,0.9940953,0.00301809,0.0002993019,0.0002446234],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9919187,0.001745666,0.00006894648,0.0008325467,0.00001325805,0.0001773271,0.0001614747,0.0002466454,0.00483537],"genre_scores_gemma":[0.9784158,0.0003635815,0.02075242,0.00002836784,0.0000183117,0.0001925231,0.0001483036,0.00004773639,0.00003295064],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02068347,"threshold_uncertainty_score":0.9999728,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.07683231206109975,"score_gpt":0.2858950647693628,"score_spread":0.2090627527082631,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}