{"id":"W1823972496","doi":"10.1002/jssc.201200322","title":"Chromatographic resolution and isotherm determination of (<i><scp>R</scp>,<scp>S</scp></i>)‐mandelic acid on <scp>C</scp>hiralcel‐<scp>OD</scp> column","year":2012,"lang":"en","type":"article","venue":"Journal of Separation Science","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland; Western University","funders":"","keywords":"Chemistry; Chromatography; Trifluoroacetic acid; Resolution (logic); Elution; Mandelic acid; Phase (matter); Enantiomer; Analytical Chemistry (journal); Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006224586,0.0004624735,0.0003893128,0.0003273676,0.0003679333,0.0003080627,0.0005453206,0.0005190077,0.0008094585],"category_scores_gemma":[0.001202292,0.0001718448,0.0004434735,0.0004110197,0.0002469751,0.0003940854,0.0001943152,0.0006762529,0.0004822771],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004619274,"about_ca_system_score_gemma":0.0006736334,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003007158,"about_ca_topic_score_gemma":0.003155578,"domain_scores_codex":[0.9994674,0.00009489388,0.0000306769,0.0001126697,0.0002290178,0.00006534942],"domain_scores_gemma":[0.9995758,0.0001371251,0.00005898627,0.00004309301,0.0001523401,0.00003275124],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002571541,0.00001460684,0.0001817325,0.00002236813,0.000004307935,0.00001160307,0.00001682852,0.0000910777,0.9971214,0.00008774315,0.00003152112,0.002391109],"study_design_scores_gemma":[0.000002737325,0.00004393232,0.0006467442,0.000001892231,0.0000073185,0.00008176934,0.00001326576,0.002025534,0.9966578,0.00003021351,0.0004832519,0.000005350327],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9210956,0.002106969,0.07191157,0.0001755955,0.00005342327,0.0001000091,0.0004662614,0.000476896,0.003613577],"genre_scores_gemma":[0.9385583,0.001684491,0.05533081,0.00009039722,0.00002064771,0.0001285301,0.0005463663,0.00009802929,0.003542394],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003007158,"threshold_uncertainty_score":0.0059793,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01884513618683554,"score_gpt":0.2857422801261967,"score_spread":0.2668971439393611,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}