{"id":"W1830837290","doi":"10.1002/cctc.201500348","title":"An Iron Catalyst for Asymmetric Alkene Hydrosilylation","year":2015,"lang":"en","type":"article","venue":"ChemCatChem","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hydrosilylation; Alkene; Catalysis; Chemistry; Organic chemistry; Polymer chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003312998,0.0002125299,0.0002502659,0.0002090096,0.00009304632,0.00006116904,0.0003510886,0.0002035362,0.0001245786],"category_scores_gemma":[0.0003298148,0.0002187151,0.000139548,0.0009624857,0.0000395659,0.0002690713,0.00003890397,0.0001132143,0.0001500755],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002657489,"about_ca_system_score_gemma":0.000107314,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005817225,"about_ca_topic_score_gemma":0.000005378105,"domain_scores_codex":[0.9985085,0.000008432087,0.0003265788,0.0004495935,0.00038849,0.0003183737],"domain_scores_gemma":[0.9985186,0.00007401051,0.0001705573,0.0006110209,0.0002411267,0.0003846658],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002426778,0.001579556,0.008059088,0.0004254789,0.0002931278,0.00001142216,0.003283712,0.0003988175,0.6180266,0.001042028,0.03140532,0.3352322],"study_design_scores_gemma":[0.001250273,0.00003219582,0.00006268726,0.000005589424,0.00009597751,0.000006790074,0.0007092799,0.006019855,0.9656185,0.0002832433,0.02558359,0.0003320501],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9126635,0.0007641048,0.005577912,0.000351371,0.0001780084,0.0002149124,0.00009103525,0.0004640797,0.07969514],"genre_scores_gemma":[0.9935285,0.000008253087,0.001367321,0.0001139615,0.000379813,0.0001030205,0.001478326,0.00004849117,0.002972254],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3475919,"threshold_uncertainty_score":0.8918943,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02619406940381017,"score_gpt":0.2759844015642233,"score_spread":0.2497903321604131,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}