{"id":"W1835627409","doi":"10.1039/c5cc04340a","title":"A platinum shell for ultraslow ligand exchange: unmodified DNA adsorbing more stably on platinum than thiol and dithiol on gold","year":2015,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"China Scholarship Council; Natural Sciences and Engineering Research Council of Canada; National Natural Science Foundation of China","keywords":"Platinum; Dithiol; Thiol; Colloidal gold; Ligand (biochemistry); Chemistry; Platinum nanoparticles; Nanoparticle; DNA; Plasmon; Nanotechnology; Materials science; Organic chemistry; Catalysis; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001400285,0.0003331755,0.0001730842,0.0001857923,0.0001351683,0.0002614706,0.0003557235,0.0003630612,0.001102612],"category_scores_gemma":[0.0002970664,0.0002305808,0.0001718713,0.0001549645,0.0001736431,0.0002365976,0.0002469624,0.0003672767,0.0004700347],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003344645,"about_ca_system_score_gemma":0.0001840169,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006881232,"about_ca_topic_score_gemma":0.001021837,"domain_scores_codex":[0.9998339,0.0000158939,0.00001307478,0.00006328041,0.00005803245,0.0000156871],"domain_scores_gemma":[0.9998645,0.00002917868,0.00002626424,0.00002277359,0.0000282724,0.00002906462],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000009549743,0.000003542512,0.0000215369,0.00001486838,0.000001967882,0.000009250783,0.000006478704,0.00002611799,0.9990582,0.00003769605,0.00001461959,0.0007961019],"study_design_scores_gemma":[0.00000252321,0.00003230131,0.0002077752,8.223286e-7,0.000004047658,0.00005070546,0.000002207583,0.0004753642,0.9985723,0.00001154429,0.0006386783,0.000001744762],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9510207,0.001755209,0.04246579,0.0002202509,0.0001100066,0.00006844902,0.0001983246,0.0004928546,0.003668462],"genre_scores_gemma":[0.9653423,0.0006787623,0.02668197,0.0001159957,0.00001315677,0.00003274472,0.0002663853,0.00008298833,0.00678576],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001102612,"threshold_uncertainty_score":0.003688633,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04719943315839411,"score_gpt":0.3182899679895096,"score_spread":0.2710905348311155,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}