{"id":"W1840550852","doi":"10.1039/c5cc04069h","title":"Blue-green emissive cationic iridium(<scp>iii</scp>) complexes using partially saturated strongly-donating guanidyl-pyridine/-pyrazine ancillary ligands","year":2015,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Iridium; Pyrazine; Cationic polymerization; Microsecond; Chemistry; Pyridine; Ligand (biochemistry); Quantum yield; Photoluminescence; Photochemistry; Yield (engineering); Luminescence; Medicinal chemistry; Stereochemistry; Polymer chemistry; Materials science; Organic chemistry; Fluorescence; Receptor; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002419658,0.0005474112,0.0004486516,0.0001658435,0.0002328111,0.0005345923,0.0007733462,0.0005059398,0.0009242517],"category_scores_gemma":[0.0002669219,0.0002467685,0.0001933554,0.0002608837,0.0003373784,0.0003350504,0.0005239227,0.0004454523,0.0003129937],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000520648,"about_ca_system_score_gemma":0.0002009875,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005956414,"about_ca_topic_score_gemma":0.0008276346,"domain_scores_codex":[0.999741,0.0000514725,0.00001486223,0.00006794072,0.00006170995,0.00006291231],"domain_scores_gemma":[0.9998877,0.00001710772,0.00003376965,0.00001380904,0.00001762612,0.00003004515],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000156008,0.00001891571,0.00005093675,0.0001065546,0.00000720785,0.0000562788,0.00002261866,0.0001861356,0.9956093,0.0002539382,0.0001494102,0.003382675],"study_design_scores_gemma":[0.00003986702,0.0001917023,0.0002989151,0.00000642983,0.000009474991,0.0001804651,0.000007642934,0.0006267278,0.9967521,0.00002807885,0.001850341,0.000008202675],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9824082,0.00143129,0.0104062,0.0001234556,0.00003914739,0.00009990499,0.0001698087,0.0005549179,0.004767101],"genre_scores_gemma":[0.9888732,0.0006075256,0.008370025,0.00006287668,0.00001000841,0.00007186339,0.0001746255,0.00006053201,0.001769313],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009242517,"threshold_uncertainty_score":0.003777564,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.07159864115464538,"score_gpt":0.3040605473472164,"score_spread":0.232461906192571,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}