{"id":"W1840550852","doi":"10.1039/c5cc04069h","title":"Blue-green emissive cationic iridium(<scp>iii</scp>) complexes using partially saturated strongly-donating guanidyl-pyridine/-pyrazine ancillary ligands","year":2015,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Iridium; Pyrazine; Cationic polymerization; Microsecond; Chemistry; Pyridine; Ligand (biochemistry); Quantum yield; Photoluminescence; Photochemistry; Yield (engineering); Luminescence; Medicinal chemistry; Stereochemistry; Polymer chemistry; Materials science; Organic chemistry; Fluorescence; Receptor; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0005196278,0.0003736968,0.0004450602,0.0001245032,0.0003443028,0.0001661353,0.001816532,0.0002643568,0.00001076359],"category_scores_gemma":[0.001346754,0.0004047612,0.0001153419,0.0009892046,0.0003341936,0.0003304831,0.0008967702,0.00100359,0.00009668586],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007242193,"about_ca_system_score_gemma":0.0003827334,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000179617,"about_ca_topic_score_gemma":0.00007067309,"domain_scores_codex":[0.997506,0.0001037563,0.0007327627,0.0003736809,0.0005589099,0.000724911],"domain_scores_gemma":[0.9957925,0.0008282731,0.0001604332,0.002057004,0.0006706291,0.0004911476],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000006301325,0.0001246243,0.001015163,0.00008642585,0.0001820534,0.000004811423,0.002542103,0.002261462,0.9865059,0.0003693261,0.006650768,0.0002510452],"study_design_scores_gemma":[0.0007673184,0.00002405431,0.0001209524,0.00009425881,0.00006336796,0.00003222077,0.0009424748,0.2145598,0.777321,0.0001140382,0.005724035,0.0002364231],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9899644,0.003346296,0.0006493098,0.0007771826,0.0001281005,0.0003998884,0.00006497231,0.0007949811,0.003874852],"genre_scores_gemma":[0.9927112,0.0001805151,0.005954836,0.00005383299,0.0002792776,0.00005163601,0.000484241,0.0001190221,0.0001654337],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2122984,"threshold_uncertainty_score":0.9998404,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.07159864115464538,"score_gpt":0.3040605473472164,"score_spread":0.232461906192571,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}