{"id":"W1851780793","doi":"10.1139/cjc-2013-0377","title":"Solvent effects on nonlinear optical response of certain tetrammineruthenium(II) complexes of modified 1,10-phenanthrolines","year":2013,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Nonlinear Optical Materials Research","field":"Materials Science","cited_by":91,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Hyperpolarizability; Polarizability; Chemistry; Solvent; Dichloromethane; Solvatochromism; Solvent effects; Density functional theory; Nonlinear optical; Acetonitrile; Polarity (international relations); Acetone; Computational chemistry; Physical chemistry; Organic chemistry; Nonlinear system; Molecule","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0008747526,0.0001989849,0.0005757566,0.0001365739,0.00008163965,0.00005865379,0.000621911,0.0001624462,0.002559399],"category_scores_gemma":[0.002001537,0.0001580374,0.0001528999,0.0001541781,0.00055151,0.0001065182,0.00005588872,0.0002270488,0.00004433901],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000116565,"about_ca_system_score_gemma":0.001209559,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007330325,"about_ca_topic_score_gemma":0.00007049245,"domain_scores_codex":[0.9978452,0.0001355437,0.0008164969,0.0001915015,0.0005013358,0.0005098777],"domain_scores_gemma":[0.997108,0.0006885848,0.000341336,0.0003595471,0.0006797873,0.0008226937],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006176061,0.00009536206,0.00004667972,0.000293689,0.00002160838,0.00006769824,0.00009545533,0.0001072716,0.9977473,0.00003272631,0.0005928756,0.0002817085],"study_design_scores_gemma":[0.0006962628,0.0004603842,0.0005934058,0.0002851573,0.00001635218,0.00005675188,0.00008017066,0.0001785872,0.9969245,0.0001714319,0.0003951364,0.0001418978],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979672,0.000095069,0.00003209131,0.0009293977,0.0001798295,0.0001531232,0.00009723658,0.000005722404,0.0005402683],"genre_scores_gemma":[0.9960999,0.000003688638,0.003120315,0.00003725465,0.0003798433,0.000005036074,0.000004911655,0.00002675192,0.0003223093],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003088223,"threshold_uncertainty_score":0.9983524,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01853572474941055,"score_gpt":0.2699188932373203,"score_spread":0.2513831684879098,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}