{"id":"W1855063115","doi":"10.1016/j.ica.2014.07.023","title":"Mechanistic insight into carbon–fluorine cleavage with a ( Pr3P)2Ni source: Characterization of ( Pr3P)2NiC6F5 as a significant Ni(I) byproduct in the activation of C6F6","year":2014,"lang":"en","type":"article","venue":"Inorganica Chimica Acta","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":31,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Hexafluorobenzene; Adduct; Fluorine; Phosphine; Anthracene; Medicinal chemistry; Selectivity; Photochemistry; Stereochemistry; Organic chemistry; Molecule; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0009107108,0.0004007487,0.0005835308,0.0001658089,0.0001244996,0.00002213786,0.000876486,0.0003875962,0.0003882812],"category_scores_gemma":[0.0008542308,0.0003150114,0.00007189462,0.000867205,0.0003201348,0.0001453493,0.000199416,0.000999196,0.0000137697],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000146398,"about_ca_system_score_gemma":0.0002823038,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001439766,"about_ca_topic_score_gemma":0.00002753389,"domain_scores_codex":[0.9970914,0.0005728288,0.0008639959,0.0006001064,0.0004439603,0.0004276781],"domain_scores_gemma":[0.9975322,0.0005870136,0.0007208358,0.0008444028,0.0001909466,0.0001246276],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006375865,0.000746401,0.002723792,0.0002758735,0.0001255261,0.000003417802,0.005572469,0.000006855792,0.9889406,0.0003632611,0.0001170006,0.0004872292],"study_design_scores_gemma":[0.001665423,0.0004393152,0.006417935,0.00006870083,0.0001894682,0.00004060764,0.0002254287,0.000655918,0.9833609,0.0002066959,0.006392885,0.0003367587],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942398,0.00001126882,0.0000614264,0.002465014,0.0002369833,0.000784811,0.00001960999,0.00007755805,0.002103509],"genre_scores_gemma":[0.9984617,0.00005458909,0.0001288962,0.0005699697,0.0003467926,0.00005744278,0.0001070778,0.00007885126,0.000194722],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006275884,"threshold_uncertainty_score":0.9999302,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02455499347011645,"score_gpt":0.3091191165737235,"score_spread":0.2845641231036071,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}