{"id":"W1857437888","doi":"10.1039/c5nj00807g","title":"Synthesis of unsymmetrical 5,6-POCOP′-type pincer complexes of nickel(<scp>ii</scp>): impact of nickelacycle size on structures and spectroscopic properties","year":2015,"lang":"en","type":"article","venue":"New Journal of Chemistry","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Pincer movement; Nickel; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000419306,0.0001998552,0.0006704709,0.0001035474,0.00004075616,0.00002935121,0.0004699976,0.0001083591,0.0004057754],"category_scores_gemma":[0.004119684,0.000146658,0.0001408307,0.000277792,0.0003437533,0.000161008,0.0001120138,0.0001810019,0.000001632197],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009278964,"about_ca_system_score_gemma":0.0005385451,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001406412,"about_ca_topic_score_gemma":0.000001741399,"domain_scores_codex":[0.998017,0.00007836186,0.0008092087,0.0001787182,0.0006986278,0.0002180557],"domain_scores_gemma":[0.9971275,0.0007336549,0.001087193,0.0002758504,0.0005542619,0.0002215433],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001725312,0.0001154717,0.002969167,0.000219496,0.0000463446,0.000002405813,0.0002715383,0.0002104226,0.9903965,0.00004900566,0.005066342,0.0004807672],"study_design_scores_gemma":[0.000774515,0.0007203213,0.01364116,0.0002147277,0.00005258709,0.0000527598,0.0002111712,0.00002830726,0.9825976,0.001531115,0.0001077483,0.00006794482],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9959351,0.001730029,0.00002577935,0.0001001444,0.0001321525,0.00008132614,0.0000208796,0.000008279556,0.001966288],"genre_scores_gemma":[0.9967806,0.00004639555,0.002653684,0.00001179904,0.000163583,7.767912e-7,5.047685e-7,0.00001591875,0.0003267244],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01067199,"threshold_uncertainty_score":0.5980541,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03061239529730012,"score_gpt":0.2867320240367667,"score_spread":0.2561196287394665,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}