{"id":"W1860505835","doi":"10.1039/c5dt03018h","title":"Transition metal-mediated donor–acceptor coordination of low-oxidation state Group 14 element halides","year":2015,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Alberta Hospital Edmonton; University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation","keywords":"Halide; Transition metal; Acceptor; Chemistry; Oxidation state; Main group element; Coordination complex; Group (periodic table); Metal; Photochemistry; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001360601,0.0002155586,0.0001715066,0.00007711815,0.00009302246,0.0002184492,0.0003911158,0.0001606277,0.00137793],"category_scores_gemma":[0.0001512684,0.0001196625,0.00009930829,0.00007401735,0.0001579632,0.0001470312,0.0002521045,0.0002186328,0.0003295593],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002712454,"about_ca_system_score_gemma":0.0001233723,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000563639,"about_ca_topic_score_gemma":0.000858987,"domain_scores_codex":[0.9998944,0.00001586518,0.000007405564,0.00002158407,0.00002412771,0.00003668519],"domain_scores_gemma":[0.9999498,0.000009058883,0.00001190163,0.000008348563,0.000007535828,0.00001339405],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001919393,0.00001974614,0.000168035,0.00004397951,0.000008390668,0.00007064051,0.00004172432,0.0001640742,0.9975373,0.0002366794,0.00004727569,0.001470219],"study_design_scores_gemma":[0.000007947946,0.00006362072,0.0002786556,7.410212e-7,0.00000304195,0.00002774005,0.000006067157,0.0003332782,0.9987692,0.00001159372,0.0004962265,0.000001761691],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9967803,0.0001422084,0.001223557,0.00001478442,0.000007069081,0.00001525408,0.00005403432,0.00005615171,0.001706717],"genre_scores_gemma":[0.9980477,0.00007396036,0.000640124,0.000006609849,0.000001676645,0.000004923832,0.00007994841,0.00001078144,0.001134304],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00137793,"threshold_uncertainty_score":0.004609644,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01898899519577941,"score_gpt":0.2295028555837217,"score_spread":0.2105138603879423,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}