{"id":"W1860878983","doi":"10.1002/chem.201500964","title":"Ultraviolet Photolysis Studies on XeO<sub>4</sub> in Noble‐Gas and F<sub>2</sub> Matrices and the Formation and Characterization of a New Xe<sup>VIII</sup> Oxide, (η<sup>2</sup>‐O<sub>2</sub>)XeO<sub>3</sub>","year":2015,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Deutsche Forschungsgemeinschaft","keywords":"Xenon; Matrix isolation; Noble gas; Photodissociation; Chemistry; Excited state; Spectroscopy; Ultraviolet; Oxide; Analytical Chemistry (journal); Irradiation; Krypton; Infrared spectroscopy; Physical chemistry; Photochemistry; Atomic physics; Materials science; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001064829,0.0002727801,0.0001423794,0.0001077025,0.0001648256,0.0001627581,0.000137977,0.0002007791,0.00187275],"category_scores_gemma":[0.0001893675,0.000126679,0.0001414064,0.0001276368,0.000166556,0.0001520668,0.0001579228,0.000231984,0.0001848582],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000167375,"about_ca_system_score_gemma":0.0000985423,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006488285,"about_ca_topic_score_gemma":0.001018722,"domain_scores_codex":[0.9999462,0.000004883525,0.000002516481,0.0000133282,0.00002136479,0.00001175604],"domain_scores_gemma":[0.9999009,0.00003855416,0.00002701971,0.000005593238,0.00001959535,0.000008257162],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006733569,0.000004978358,0.0002375104,0.00003605052,0.000004512592,0.00003136296,0.00003105198,0.00006896506,0.9984683,0.00004047455,0.00001669314,0.0009925832],"study_design_scores_gemma":[0.000004609174,0.0001396756,0.005492734,0.000005556471,0.000008769175,0.0001152234,0.00004545015,0.0003930531,0.9927408,0.00003474752,0.001015147,0.000004267475],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973221,0.0006137289,0.0010107,0.00001129643,0.000004527915,0.000006545186,0.00008148572,0.00001249145,0.0009370943],"genre_scores_gemma":[0.9961829,0.0005383834,0.001560613,0.00001107846,0.000003498182,0.000009899901,0.0001452357,0.0000144121,0.001533924],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00187275,"threshold_uncertainty_score":0.006264985,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01332335406926312,"score_gpt":0.2072626272231254,"score_spread":0.1939392731538623,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}