{"id":"W1871026626","doi":"10.1002/047084289x.rn01378","title":"(11<i>b</i><i>R</i>)-4,5-Dihydro-3<i>H</i>-dinaphtho[2,1-<i>c</i>:1′,2′-<i>e</i>]Phosphepine Borane","year":2012,"lang":"he","type":"reference-entry","venue":"Encyclopedia of Reagents for Organic Synthesis","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Toluene; Methylene; Chemistry; Proton NMR; Borane; Nuclear chemistry; Medicinal chemistry; Stereochemistry; Analytical Chemistry (journal); Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000141076,0.0004505842,0.0002311211,0.0001990282,0.0003678543,0.0002142672,0.0005154273,0.000220889,0.02289364],"category_scores_gemma":[0.0001129132,0.0002025278,0.0001020662,0.0002532612,0.0001477229,0.0003811476,0.0003838437,0.0005196797,0.01005751],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003690524,"about_ca_system_score_gemma":0.0004820594,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001130854,"about_ca_topic_score_gemma":0.001954501,"domain_scores_codex":[0.9998937,0.00001535862,0.000004177351,0.00003198894,0.00001344838,0.00004132104],"domain_scores_gemma":[0.9999563,0.000007124537,0.000008606684,0.000008082132,0.000005354735,0.000014637],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0006522299,0.00007019579,0.0002412772,0.0005709234,0.00001718349,0.0002587898,0.00004674594,0.000284055,0.979365,0.003349419,0.003727347,0.01141676],"study_design_scores_gemma":[0.0001576067,0.0007118359,0.001734071,0.00005057186,0.00002381308,0.001085318,0.00007508207,0.0009337308,0.8983707,0.0006184584,0.0961971,0.00004180648],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"other","genre_scores_codex":[0.7465203,0.008521196,0.06407787,0.0008684253,0.001174287,0.0005130614,0.008673782,0.005175484,0.1644756],"genre_scores_gemma":[0.8947849,0.004932615,0.02020407,0.0004369408,0.00008696238,0.0003863618,0.004152064,0.0004501872,0.07456591],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.02289364,"threshold_uncertainty_score":0.07658684,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01451714888756575,"score_gpt":0.2461218385686547,"score_spread":0.2316046896810889,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}