{"id":"W1875266020","doi":"10.1562/2006-08-01-ra-992","title":"Transient Enol Isomers of Dibenzoylmethane and Avobenzone as Efficient Hydrogen Donors toward a Nitroxide Pre-fluorescent Probe†","year":2007,"lang":"en","type":"article","venue":"Photochemistry and Photobiology","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Dibenzoylmethane; Photochemistry; Chemistry; Flash photolysis; Enol; Fluorescence; Reactivity (psychology); Quenching (fluorescence); Delocalized electron; Adduct; Double bond; Physical chemistry; Organic chemistry; Catalysis; Kinetics; Reaction rate constant","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001741301,0.0002948964,0.0001568369,0.00008613386,0.00008217627,0.0001578957,0.0002261077,0.0001999328,0.000978944],"category_scores_gemma":[0.000114298,0.00007463533,0.00009501478,0.00009768131,0.0001490082,0.0001686352,0.0001075348,0.0002898971,0.0001303263],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002028061,"about_ca_system_score_gemma":0.000108132,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004582792,"about_ca_topic_score_gemma":0.0007314162,"domain_scores_codex":[0.999907,0.00002002963,0.00000500343,0.00002276728,0.00001985781,0.00002524436],"domain_scores_gemma":[0.9998939,0.00002833308,0.00002761807,0.00001030609,0.00001608461,0.0000237176],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006082269,0.000006812497,0.00003990456,0.00001423364,0.000001534413,0.000009538072,0.000009287829,0.00002025748,0.9993724,0.00006015073,0.000008120861,0.0003969008],"study_design_scores_gemma":[0.000002629102,0.00007514725,0.0002121999,8.220051e-7,0.000002479759,0.00001027328,0.000005322757,0.000143465,0.9993187,0.000007646926,0.0002204877,7.697172e-7],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9965914,0.0005037829,0.002245921,0.00002417886,0.00001110517,0.00001389694,0.00004648869,0.00002221616,0.0005410088],"genre_scores_gemma":[0.9966749,0.0002340278,0.001584157,0.00001543136,0.000003061387,0.0000120501,0.00007738443,0.000006690614,0.00139223],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000978944,"threshold_uncertainty_score":0.003274918,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008181244660512246,"score_gpt":0.2376265249032147,"score_spread":0.2294452802427024,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}