{"id":"W1884478861","doi":"10.1039/c5dt01778e","title":"Reducing zirconium(<scp>iv</scp>) phthalocyanines and the structure of a Pc<sup>4−</sup>Zr complex","year":2015,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"Burnaby Hospital; Simon Fraser University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Ring (chemistry); Dimer; Zirconium; Phthalocyanine; Chloride; Crystallography; Cyclic voltammetry; Proton NMR; Medicinal chemistry; Nuclear magnetic resonance spectroscopy; Stereochemistry; Analytical Chemistry (journal); Inorganic chemistry; Physical chemistry; Electrochemistry; Organic chemistry; Electrode","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000101165,0.0002587716,0.0001123438,0.00008999785,0.00009952235,0.0002011671,0.0003220411,0.0002159437,0.0009135859],"category_scores_gemma":[0.0001534905,0.000121338,0.00009881029,0.0001418442,0.0001804838,0.0001781807,0.0001605997,0.0003676526,0.0002842156],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003246506,"about_ca_system_score_gemma":0.0001347087,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007345883,"about_ca_topic_score_gemma":0.0006768581,"domain_scores_codex":[0.9999003,0.00001343161,0.000005404919,0.00001983617,0.00004094676,0.00002001869],"domain_scores_gemma":[0.9999521,0.000006379312,0.00001738846,0.000006703862,0.000009941311,0.000007583138],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003776209,0.000005623008,0.0000716287,0.00002439851,0.000002960948,0.00001910407,0.00001229391,0.0001154921,0.9985003,0.000119061,0.00002742016,0.001063976],"study_design_scores_gemma":[0.00000415879,0.00004546602,0.0004196791,0.000001018543,0.000003455333,0.00005251199,0.000004866582,0.0002541234,0.9978731,0.00001515032,0.001324783,0.000001655449],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9929079,0.0005388339,0.004543826,0.00007713425,0.000007833387,0.00003689534,0.0002069705,0.0001045305,0.001576189],"genre_scores_gemma":[0.9922959,0.0002854136,0.004904583,0.00002908402,0.000005534317,0.00001907304,0.0004895036,0.00002844049,0.001942619],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009135859,"threshold_uncertainty_score":0.003056288,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02871890527030024,"score_gpt":0.2556602573198762,"score_spread":0.226941352049576,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}