{"id":"W1885617869","doi":"10.1039/c5cc02804c","title":"Red, far-red, and near infrared photoswitches based on azonium ions","year":2015,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Photochromic and Fluorescence Chemistry","field":"Materials Science","cited_by":116,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Concordia University; Toronto Public Health","funders":"","keywords":"Absorbance; Ion; Aqueous solution; Infrared; Chemistry; Photochemistry; Near-infrared spectroscopy; Far infrared; Physical chemistry; Organic chemistry; Optics; Physics; Chromatography","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001170254,0.0002998855,0.0001665214,0.0001614596,0.0001202537,0.0002473373,0.000213313,0.0003179392,0.0008682652],"category_scores_gemma":[0.0001454644,0.0001355588,0.0001495412,0.0001054418,0.0002589443,0.0002892301,0.0001718867,0.0003463821,0.0002101703],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001951588,"about_ca_system_score_gemma":0.00008148233,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000154697,"about_ca_topic_score_gemma":0.0002442454,"domain_scores_codex":[0.9999286,0.000009312587,0.000004079946,0.00002001276,0.00001750562,0.00002050944],"domain_scores_gemma":[0.9999381,0.0000175356,0.00001857286,0.00000540993,0.000006702067,0.00001370483],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000629345,0.0000059321,0.00005742583,0.00002099715,0.000002523266,0.00005162519,0.00001119406,0.0001019436,0.9982194,0.0002648724,0.00002408024,0.001177066],"study_design_scores_gemma":[0.0000092143,0.0002128901,0.0006167659,0.000002656587,0.000007020795,0.0001213296,0.000007040534,0.0007907005,0.9976476,0.00007064549,0.0005094024,0.000004831958],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9933785,0.0006734199,0.002858882,0.00004998283,0.00002617918,0.00001317649,0.00006600114,0.00008835129,0.002845631],"genre_scores_gemma":[0.9964161,0.0003875125,0.00146858,0.00002856849,0.000008619959,0.00001444126,0.00005645982,0.00001176075,0.001607991],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008682652,"threshold_uncertainty_score":0.002904594,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04731060562937723,"score_gpt":0.2782543819072022,"score_spread":0.230943776277825,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}