{"id":"W1888431346","doi":"10.1039/c5nj00624d","title":"Efficient and selective azidation of per-O-acetylated sugars using ultrasound activation: application to the one-pot synthesis of 1,2,3-triazole glycosides","year":2015,"lang":"en","type":"article","venue":"New Journal of Chemistry","topic":"Click Chemistry and Applications","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Institute of Cancer Research; Canceropôle Provence-Alpes-Côte d’Azur; Institut National Du Cancer; Association pour la Recherche sur le Cancer","keywords":"Chemistry; Acetylation; Glycoside; Triazole; Combinatorial chemistry; Organic chemistry; Click chemistry; Biochemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002758064,0.0001408506,0.0002792331,0.00002660164,0.00007124527,0.00002172814,0.0002477292,0.0001300377,0.00007513319],"category_scores_gemma":[0.000656017,0.0001233862,0.00008200393,0.0002739421,0.00008023001,0.00005599529,0.00003892056,0.0002131009,9.255108e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001447263,"about_ca_system_score_gemma":0.0002868526,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003761963,"about_ca_topic_score_gemma":0.000001097014,"domain_scores_codex":[0.9987419,0.0000140208,0.0005748592,0.0001693233,0.0003704773,0.0001294762],"domain_scores_gemma":[0.9977804,0.0003760503,0.000844127,0.0002807824,0.0005436521,0.0001750293],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001710541,0.0001302634,0.0004568063,0.0001121985,0.00007513336,1.609412e-7,0.0005117873,0.006893389,0.9897665,0.000007980703,0.0002408069,0.001633871],"study_design_scores_gemma":[0.0004702511,0.00001187171,0.000192608,0.0001688181,0.0001164132,0.00007844532,0.001006348,0.0006633704,0.9966798,0.0001333854,0.0003690911,0.0001096333],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9944726,0.0001049955,0.003362038,0.0004182692,0.00001143596,0.00007941885,0.00001867664,0.000009254649,0.00152327],"genre_scores_gemma":[0.9977057,0.00001615596,0.001905038,0.0000116511,0.0002469124,0.00000789865,0.000008176235,0.00001465641,0.00008383597],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006913216,"threshold_uncertainty_score":0.5031542,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02482681341731285,"score_gpt":0.2709946685857137,"score_spread":0.2461678551684008,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}