{"id":"W1891907588","doi":"10.1002/ejoc.201500985","title":"Enantioselective Synthesis of Functionalized Quaternary Stereocenters","year":2015,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Stereocenter; Enantioselective synthesis; Chemistry; Stereoselectivity; Alkyl; Stereochemistry; Organic chemistry; Combinatorial chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001727164,0.0003155028,0.0005885568,0.0000457041,0.00004007038,0.00003106346,0.0007905226,0.00008956963,0.01019692],"category_scores_gemma":[0.003177245,0.000290629,0.0002945798,0.0002285741,0.000174234,0.0001240869,0.0001735591,0.0004832888,0.00003804393],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002783178,"about_ca_system_score_gemma":0.0004023724,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000139608,"about_ca_topic_score_gemma":7.676459e-8,"domain_scores_codex":[0.9973068,0.0002074298,0.001159668,0.0002948525,0.0007235066,0.0003076932],"domain_scores_gemma":[0.9967855,0.0003807604,0.001327768,0.0005169415,0.0005870795,0.0004020098],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003667769,0.0002217436,0.001359461,0.0002166267,0.0003294518,0.0002294245,0.0003527327,0.000003990807,0.989862,9.441184e-7,0.00141074,0.0056461],"study_design_scores_gemma":[0.001744248,0.00003931094,0.0001249375,0.0003626616,0.0001874172,0.001873991,0.00124703,0.00001208251,0.9860645,0.00004178537,0.008044685,0.0002573655],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9020972,0.000584236,0.001382524,0.000216728,0.0002970046,0.00002744644,0.00002270693,0.00005344758,0.09531875],"genre_scores_gemma":[0.9934576,0.00004796734,0.002664542,0.00002300498,0.0006930025,6.902793e-7,0.00000423299,0.0001052675,0.003003693],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09231506,"threshold_uncertainty_score":0.9999546,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02720726818548041,"score_gpt":0.2490703906142684,"score_spread":0.2218631224287879,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}