{"id":"W1892722803","doi":"10.1139/v11-094","title":"A partially water-soluble cationic Mn(III)–salphen complex for catalytic epoxidation","year":2011,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Polyoxometalates: Synthesis and Applications","field":"Materials Science","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Cationic polymerization; Chemistry; Catalysis; Homogeneous; Salt (chemistry); Polymer chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003330117,0.00009973999,0.0001783888,0.00004450485,0.000177619,0.00007574624,0.00035559,0.00006356878,0.002079342],"category_scores_gemma":[0.00006415344,0.00008430111,0.00008819796,0.00006388913,0.0000945484,0.0001697112,0.000009724186,0.00006457685,0.00006105489],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001181827,"about_ca_system_score_gemma":0.0007174495,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001197644,"about_ca_topic_score_gemma":0.001398503,"domain_scores_codex":[0.9990486,0.00001030222,0.0003907813,0.0001318678,0.0001020877,0.0003163677],"domain_scores_gemma":[0.998908,0.00002778396,0.0002176225,0.0002187124,0.0002055441,0.000422381],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000009126338,0.00001824394,0.00008255312,0.00002626518,0.0000149212,0.000003651706,0.0005001281,0.00001075401,0.9959769,0.0001029206,0.002993598,0.000260916],"study_design_scores_gemma":[0.0002307839,0.00001550423,0.0003814426,0.00002340663,0.00003852678,0.00006194796,0.00009382872,0.00005437144,0.9824057,0.001103845,0.015476,0.0001146667],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9936209,0.0001001548,0.001676074,0.0005551976,0.0001780929,0.0001372503,0.00007530351,0.00001154446,0.0036455],"genre_scores_gemma":[0.9975012,0.000002839897,0.001274989,0.00006333944,0.0001627425,0.00002258523,0.00004056502,0.00001431312,0.0009174101],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01357125,"threshold_uncertainty_score":0.9988329,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04494805134298097,"score_gpt":0.2368370650194578,"score_spread":0.1918890136764768,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}