{"id":"W1898137896","doi":"10.1002/rcm.6163","title":"A reliable method by ultra‐performance liquid chromatography coupled with tandem mass spectrometry to quantify and confirm simultaneously the presence of solvent metabolites in workers' urine","year":2012,"lang":"en","type":"article","venue":"Rapid Communications in Mass Spectrometry","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institut de recherche Robert-Sauvé en santé et en sécurité du travail","funders":"Institut de Recherche Robert-Sauvé en Santé et en Sécurité du Travail","keywords":"Chemistry; Mandelic acid; Chromatography; Repeatability; Metabolite; Tandem mass spectrometry; Urine; Mass spectrometry; Selected reaction monitoring; Liquid chromatography–mass spectrometry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.002910588,0.001587125,0.0008779094,0.002375446,0.0007911779,0.001077882,0.001276146,0.002058941,0.001113686],"category_scores_gemma":[0.003204499,0.0007198039,0.0009408699,0.0009442645,0.001226921,0.0008960278,0.001328859,0.001704284,0.00161409],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006093006,"about_ca_system_score_gemma":0.002334543,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001466886,"about_ca_topic_score_gemma":0.002787696,"domain_scores_codex":[0.9929922,0.001335783,0.0003033185,0.001456946,0.003659297,0.0002525991],"domain_scores_gemma":[0.9976367,0.0004806446,0.0003990881,0.0002966846,0.001061894,0.0001250064],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001243694,0.000124527,0.00334686,0.000279239,0.00009326063,0.0001382803,0.0001010437,0.0002208527,0.9546561,0.0003254696,0.0005789218,0.04001113],"study_design_scores_gemma":[0.00007123906,0.000843903,0.0204319,0.0001204793,0.0001864049,0.002101155,0.0001396422,0.007720754,0.9522592,0.0006184386,0.01533003,0.0001767194],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.1838538,0.01315947,0.7913827,0.0009118383,0.0006561505,0.001440555,0.001947973,0.003240906,0.003406558],"genre_scores_gemma":[0.3874697,0.005720292,0.5912691,0.001664675,0.0002542285,0.002771236,0.001686246,0.0003001456,0.008864343],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.002910588,"threshold_uncertainty_score":0.01539284,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01335951916412809,"score_gpt":0.2739611961762973,"score_spread":0.2606016770121692,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}