{"id":"W1898629866","doi":"10.1021/jo5026354","title":"Thioboration of α,β-Unsaturated Ketones and Aldehydes toward the Synthesis of β-Sulfido Carbonyl Compounds","year":2015,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick; Mount Allison University","funders":"Natural Sciences and Engineering Research Council of Canada; Institut Català d'Investigació Química; Ministerio de Economía y Competitividad; Generalitat de Catalunya","keywords":"Chemistry; Reagent; Reactivity (psychology); Nucleophile; Aldehyde; Substrate (aquarium); Nucleophilic addition; Medicinal chemistry; Organic chemistry; Combinatorial chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002053639,0.0005159028,0.0001958177,0.0002554447,0.0001609343,0.0001564438,0.0002387991,0.0001837686,0.001464531],"category_scores_gemma":[0.0001056827,0.0001788981,0.0001811788,0.0001781033,0.0002006629,0.0002870566,0.0002369884,0.0003755578,0.0007106494],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001486313,"about_ca_system_score_gemma":0.0002398874,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003307214,"about_ca_topic_score_gemma":0.0009631889,"domain_scores_codex":[0.9998995,0.00001751232,0.000008097968,0.00001782237,0.00002640439,0.00003063764],"domain_scores_gemma":[0.9999447,0.000005028585,0.00001496411,0.000006171801,0.00001288187,0.00001616482],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001107169,0.00003274491,0.0001630298,0.0003878282,0.00001796473,0.0003397327,0.0001702243,0.0003884857,0.9858457,0.002066218,0.000353646,0.01012358],"study_design_scores_gemma":[0.00001495071,0.000372681,0.0005295216,0.00001598375,0.00002048858,0.0003708584,0.00003724392,0.0004418274,0.988214,0.0001730531,0.009797159,0.00001209837],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9351255,0.008749052,0.02885426,0.0003586959,0.0001999072,0.0001207145,0.0004140798,0.0005275777,0.0256502],"genre_scores_gemma":[0.9784062,0.004505162,0.01135852,0.00008369843,0.00004127334,0.00004661714,0.0002086518,0.00004432681,0.005305637],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001464531,"threshold_uncertainty_score":0.004899383,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02271129561037954,"score_gpt":0.2392344615076355,"score_spread":0.216523165897256,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}