{"id":"W1898629866","doi":"10.1021/jo5026354","title":"Thioboration of α,β-Unsaturated Ketones and Aldehydes toward the Synthesis of β-Sulfido Carbonyl Compounds","year":2015,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick; Mount Allison University","funders":"Natural Sciences and Engineering Research Council of Canada; Institut Català d'Investigació Química; Ministerio de Economía y Competitividad; Generalitat de Catalunya","keywords":"Chemistry; Reagent; Reactivity (psychology); Nucleophile; Aldehyde; Substrate (aquarium); Nucleophilic addition; Medicinal chemistry; Organic chemistry; Combinatorial chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00128132,0.0002053228,0.0004595061,0.00003097978,0.00005296632,0.0000250493,0.0006721859,0.0001754287,0.000223408],"category_scores_gemma":[0.001355527,0.0001204134,0.0001067688,0.000217123,0.0003716982,0.0001048225,0.0001004807,0.0003748729,6.716469e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009557094,"about_ca_system_score_gemma":0.0002960847,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002751571,"about_ca_topic_score_gemma":0.000002663583,"domain_scores_codex":[0.9983639,0.00009143173,0.0007401288,0.0001147116,0.0005289776,0.0001608385],"domain_scores_gemma":[0.9967806,0.0009499334,0.001122761,0.0004939924,0.0005585701,0.00009419414],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002150455,0.00006960169,0.000691812,0.0001811105,0.0001488812,0.000003494692,0.001208385,0.00000414406,0.9962049,0.000003825832,0.0005400444,0.0007287813],"study_design_scores_gemma":[0.0003069389,0.0000279772,0.0001741582,0.0002412048,0.000269493,0.000259991,0.004146887,0.00003869355,0.9939559,0.0003314716,0.0001266229,0.0001206913],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9946952,0.001472633,0.00005530508,0.001143254,0.00003608922,0.0000440665,0.00001530938,0.00002939742,0.00250877],"genre_scores_gemma":[0.9991176,0.0003075828,0.0003079062,0.00002010831,0.0001544669,0.000001868205,0.00000153373,0.00003073004,0.00005821018],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004422419,"threshold_uncertainty_score":0.4910314,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02271129561037954,"score_gpt":0.2392344615076355,"score_spread":0.216523165897256,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}