{"id":"W1900648284","doi":"10.1039/b201660e","title":"Protonation studies on epimeric homoallylic adamantylideneadamantyl alcohols, 4-methyleneadamantylideneadamantane, adamantylideneadamantane (AdAd) and sesquihomoadamantene, and reaction of AdAd and sesquihomoadamantene with NO2+BF4– and PhI(OH)OTs: a stable-ion NMR and theoretical (GIAO-NMR) studyElectronic supplementary information (ESI) available: representative 1D-NMR spectra and tables of cartesian coordinates. See http://www.rsc.org/suppdata/p2/b2/b201660e/","year":2002,"lang":"en","type":"article","venue":"Journal of the Chemical Society Perkin Transactions 2","topic":"Eicosanoids and Hypertension Pharmacology","field":"Biochemistry, Genetics and Molecular Biology","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"National Institutes of Health","keywords":"Carbocation; Oxonium ion; Protonation; Chemistry; Medicinal chemistry; Quenching (fluorescence); Kinetic isotope effect; Photochemistry; Alcohol; Ketone; Ion; Stereochemistry; Organic chemistry; Deuterium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0009411495,0.00067441,0.001132865,0.0002059624,0.0005234191,0.0001119057,0.0002724652,0.0003686246,0.00006010588],"category_scores_gemma":[0.0001324859,0.0004949225,0.0001917192,0.000409749,0.001824203,0.0002870969,0.0002070974,0.0007970427,5.412576e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001169187,"about_ca_system_score_gemma":0.0001154559,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001984793,"about_ca_topic_score_gemma":0.000141631,"domain_scores_codex":[0.9963164,0.0002992401,0.001293775,0.0007748902,0.0007241498,0.0005915941],"domain_scores_gemma":[0.997223,0.0003761667,0.00106084,0.0004249914,0.0006243075,0.0002907278],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002048443,0.0005799446,0.005132244,0.0008971444,0.002052119,0.00003153584,0.002093165,0.00006436707,0.982805,0.0004321261,0.001514938,0.002348968],"study_design_scores_gemma":[0.0134648,0.006938399,0.01455784,0.001379405,0.003673216,0.006028214,0.01688858,0.006720893,0.9246561,0.0006003508,0.003514916,0.001577312],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9840078,0.01206925,0.0002419447,0.00215206,0.00008700864,0.00108982,0.0003087324,0.00001584365,0.00002757162],"genre_scores_gemma":[0.9668132,0.03095811,0.001375928,0.0004586787,0.0001216721,0.00006044669,0.00005794138,0.00005753041,0.00009646636],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05814893,"threshold_uncertainty_score":0.9997503,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01401984240001942,"score_gpt":0.2542084237602817,"score_spread":0.2401885813602623,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}