{"id":"W1907539551","doi":"10.1115/1.4031013","title":"Radiolysis of Supercritical Water at 400°C: A Sensitivity Study of the Density Dependence of the Yield of Hydrated Electrons on the (eaq−+eaq−) Reaction Rate Constant","year":2015,"lang":"en","type":"article","venue":"Journal of Nuclear Engineering and Radiation Science","topic":"Subcritical and Supercritical Water Processes","field":"Engineering","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Nuclear Laboratories; Université de Sherbrooke","funders":"Natural Resources Canada; Natural Sciences and Engineering Research Council of Canada","keywords":"Supercritical fluid; Arrhenius equation; Extrapolation; Solvated electron; Radiolysis; Drop (telecommunication); Reaction rate constant; Yield (engineering); Thermodynamics; Materials science; Chemistry; Analytical Chemistry (journal); Activation energy; Physical chemistry; Aqueous solution; Kinetics; Physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004896949,0.0003425492,0.0003256394,0.0002739232,0.0001387729,0.0002687817,0.0004668796,0.0003744128,0.0005016709],"category_scores_gemma":[0.001578427,0.0002902184,0.0003011602,0.0003002231,0.0004809173,0.0003792629,0.0003086345,0.0005092708,0.0001242031],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005660723,"about_ca_system_score_gemma":0.0002306787,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003193011,"about_ca_topic_score_gemma":0.001392392,"domain_scores_codex":[0.9997408,0.00004172343,0.00001271421,0.00006031654,0.0001002402,0.00004418942],"domain_scores_gemma":[0.999184,0.000508757,0.0001122978,0.00005911641,0.0001096583,0.00002611304],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005323217,0.00008185967,0.007725723,0.0001298655,0.00005935443,0.0001233385,0.0002017682,0.02667905,0.9600974,0.0003972244,0.00005216942,0.003919977],"study_design_scores_gemma":[0.00001239067,0.0002850582,0.005836892,0.000003824652,0.00002339101,0.00004260155,0.00003562407,0.04890407,0.9446307,0.00006325303,0.0001436148,0.0000185572],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972751,0.0001016447,0.002252092,0.00001684483,0.000002506938,0.00001343835,0.00005891563,0.00003626974,0.0002432087],"genre_scores_gemma":[0.9990175,0.0001138271,0.0006874069,0.000006902665,0.000001217273,0.00000913238,0.00005934966,0.000005779903,0.00009901365],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003193011,"threshold_uncertainty_score":0.006348848,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01561862224351029,"score_gpt":0.2081122164930016,"score_spread":0.1924935942494913,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}