{"id":"W1909828497","doi":"10.1002/adsc.201500453","title":"Copper(I) Complexes Bearing Carbenes Beyond Classical N‐Heterocyclic Carbenes: Synthesis and Catalytic Activity in “Click Chemistry”","year":2015,"lang":"en","type":"article","venue":"Advanced Synthesis & Catalysis","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":76,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Royal Society; Ministère de l'Économie, de la Science et de l'Innovation - Québec; Engineering and Physical Sciences Research Council; U.S. Department of Energy","keywords":"Mesoionic; Chemistry; Carbene; Cycloaddition; Catalysis; Copper; Iminium; Click chemistry; Combinatorial chemistry; Organometallic chemistry; Alkyl; Organic chemistry; Polymer chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.000328245,0.0009488968,0.001578002,0.0001569712,0.0002515572,0.0001567538,0.0009364838,0.0005791434,0.0003488493],"category_scores_gemma":[0.001760058,0.001008841,0.0003764839,0.000587424,0.0005613718,0.0007005746,0.0007000557,0.0006910382,0.00004160256],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001011481,"about_ca_system_score_gemma":0.0001576412,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007992788,"about_ca_topic_score_gemma":0.0003152239,"domain_scores_codex":[0.9953005,0.00007115996,0.0009772484,0.001702647,0.0008231727,0.001125246],"domain_scores_gemma":[0.9956059,0.001350682,0.0004283283,0.001763528,0.0001302147,0.0007213375],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001722726,0.0002899894,0.005380683,0.0004510065,0.0002907047,0.000060803,0.0004032184,0.00009474011,0.9606481,0.00001149715,0.00008902635,0.03210801],"study_design_scores_gemma":[0.0008570984,0.00001224811,0.0005503825,0.0002656961,0.0004811845,0.0001323827,0.001633828,0.0004291292,0.9921463,0.0001313503,0.002271149,0.001089288],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9874695,0.00156619,0.00003312607,0.0003922626,0.000106198,0.0001407151,0.0001533437,0.0002747087,0.009863989],"genre_scores_gemma":[0.9978264,0.000383995,0.0003187761,0.00006157305,0.0002700637,0.000246472,0.00008183899,0.0001701964,0.0006407051],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03149822,"threshold_uncertainty_score":0.9992362,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01592165490102414,"score_gpt":0.2460535170905559,"score_spread":0.2301318621895318,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}