{"id":"W1915443664","doi":"10.1021/acs.organomet.5b00546","title":"Diverging Pathways in the Activation of Allenes with Lewis Acids and Bases: Addition, 1,2-Carboboration, and Cyclization","year":2015,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":47,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Studienstiftung des Deutschen Volkes; Canada Research Chairs; Verband der Chemischen Industrie","keywords":"Allene; Chemistry; Lewis acids and bases; Nucleophile; Ketone; Base (topology); Frustrated Lewis pair; Medicinal chemistry; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001647522,0.0003867657,0.0001257297,0.0004035446,0.0002036616,0.0004319797,0.0002997175,0.0003423873,0.002656794],"category_scores_gemma":[0.0001622276,0.0002498364,0.0001330846,0.0001566562,0.0003811656,0.000667791,0.0003093288,0.0004764478,0.0004893433],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001851424,"about_ca_system_score_gemma":0.0001462287,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003398622,"about_ca_topic_score_gemma":0.0007622103,"domain_scores_codex":[0.9999266,0.00001010035,0.00000299455,0.00002052186,0.000017797,0.00002205089],"domain_scores_gemma":[0.9999529,0.00001667496,0.00001013368,0.000006475532,0.000004041367,0.000009779283],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00015648,0.00001448901,0.0002057071,0.00007196717,0.000008847906,0.0003861502,0.0001251935,0.0003828355,0.9906828,0.002082831,0.0001154438,0.005767232],"study_design_scores_gemma":[0.00002289977,0.0001837966,0.001268331,0.00001004963,0.000007279667,0.0005282986,0.00009365485,0.001434909,0.9911378,0.001041707,0.004246397,0.0000247756],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9771035,0.002353946,0.007244438,0.0001387362,0.00002816903,0.00003762028,0.0001378063,0.0002517661,0.01270402],"genre_scores_gemma":[0.9918993,0.001001158,0.004305451,0.00004236027,0.000008027004,0.00002657209,0.0001012712,0.00002458482,0.002591324],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002656794,"threshold_uncertainty_score":0.008887827,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02077236169770172,"score_gpt":0.2114397973637159,"score_spread":0.1906674356660142,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}