{"id":"W1916224281","doi":"10.1002/bmc.2745","title":"Dried blood spot on‐card derivatization: an alternative form of sample handling to overcome the instability of thiorphan in biological matrix","year":2012,"lang":"en","type":"article","venue":"Biomedical Chromatography","topic":"Biosimilars and Bioanalytical Methods","field":"Immunology and Microbiology","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"BioPhage Pharma (Canada)","funders":"","keywords":"Thiorphan; Chemistry; Chromatography; Derivatization; Matrix (chemical analysis); Elution; High-performance liquid chromatography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001057193,0.0009181774,0.0005807285,0.0006190924,0.0002856655,0.0005106474,0.0009085875,0.0008696653,0.002352512],"category_scores_gemma":[0.0008787333,0.0003235537,0.0004136486,0.0005078432,0.0005108358,0.0004929859,0.0004753873,0.0006954292,0.001250585],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002587677,"about_ca_system_score_gemma":0.0003899887,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006124285,"about_ca_topic_score_gemma":0.001042904,"domain_scores_codex":[0.9989302,0.000247758,0.00004552347,0.0002899893,0.0004344383,0.00005218705],"domain_scores_gemma":[0.9994367,0.0001216544,0.0001259099,0.00009778584,0.000188923,0.00002901638],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002484218,0.00004569205,0.0004067109,0.0002893991,0.00006238779,0.0001453707,0.00006072966,0.00008652572,0.9779316,0.0002217612,0.0005167677,0.01998476],"study_design_scores_gemma":[0.00002676746,0.0005585443,0.002389974,0.00001489109,0.00007505281,0.00146673,0.00003639239,0.001619881,0.9806234,0.00015564,0.01300204,0.00003077192],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.503526,0.01836063,0.460454,0.0009575883,0.001144092,0.001299706,0.001758856,0.003239501,0.009259636],"genre_scores_gemma":[0.5689449,0.01049713,0.3942285,0.001874341,0.0003432004,0.0004573115,0.002159477,0.0003736619,0.02112143],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002352512,"threshold_uncertainty_score":0.007869899,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03924324602963906,"score_gpt":0.322696027232027,"score_spread":0.2834527812023879,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}