{"id":"W1917081990","doi":"10.1002/chem.201502920","title":"Formation of the Main Cores Present in Natural Products by Tandem Additions","year":2015,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hypervalent molecule; Reagent; Chemistry; Stereoselectivity; Substituent; Indole test; Tandem; Bicyclic molecule; Alkyl; Combinatorial chemistry; Organic chemistry; Stereochemistry; Catalysis; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000391074,0.0001796213,0.000159952,0.00001575187,0.0001203486,0.00005744882,0.0005037031,0.00004481898,0.0005246369],"category_scores_gemma":[0.0007580533,0.0001416502,0.00008529165,0.000241101,0.0001529667,0.0001611011,0.0001434007,0.0008004703,0.00001493377],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003318178,"about_ca_system_score_gemma":0.0001937255,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001997498,"about_ca_topic_score_gemma":9.100309e-7,"domain_scores_codex":[0.9985987,0.00007831168,0.0004927251,0.0001973059,0.0003822078,0.00025073],"domain_scores_gemma":[0.998763,0.00004182995,0.0004335949,0.0003991942,0.000216118,0.000146269],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001467559,0.0001063019,0.000267034,0.00006886179,0.00001690033,0.00002112551,0.0003247048,0.00001980001,0.9136817,7.993935e-7,0.08520269,0.0002754004],"study_design_scores_gemma":[0.0009718943,0.000005651013,0.0002721701,0.0001752075,0.00001820756,0.0009797266,0.001335948,0.0003872414,0.9664626,0.00004152802,0.02918567,0.0001641239],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9643906,0.0003436972,0.00002955235,0.001031521,0.0001189814,0.00005504972,0.0001307812,0.00003185472,0.03386793],"genre_scores_gemma":[0.9931956,0.00001832744,0.00008969186,0.00001618631,0.0004715275,0.000003353028,0.00008726365,0.00003085159,0.006087214],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05601702,"threshold_uncertainty_score":0.5776325,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02152069539776571,"score_gpt":0.2257858722588272,"score_spread":0.2042651768610615,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}