{"id":"W1919078165","doi":"10.1002/ejic.201402495","title":"Elucidating the Origin of Enhanced Phosphorescence Emission in the Solid State (EPESS) in Cyclometallated Iridium Complexes","year":2014,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Phosphorescence; Iridium; Chemistry; Ligand (biochemistry); Excited state; Photochemistry; Stacking; Ring (chemistry); Solid-state; Chelation; Triplet state; Crystallography; Molecule; Fluorescence; Physical chemistry; Inorganic chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.002819119,0.0001877073,0.0003080484,0.00006354447,0.0000482191,0.00005521788,0.00112503,0.00003460679,0.0001204639],"category_scores_gemma":[0.0007092166,0.0001196046,0.0000704518,0.0005986415,0.00008964689,0.00009583597,0.0001153418,0.000979644,0.0000123827],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000109465,"about_ca_system_score_gemma":0.00006251434,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006780428,"about_ca_topic_score_gemma":0.000002210183,"domain_scores_codex":[0.9978122,0.000328805,0.0009010425,0.0001485426,0.0004737504,0.0003356285],"domain_scores_gemma":[0.9988125,0.0003209312,0.0002893663,0.0003928159,0.0001100814,0.0000742867],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002024096,0.00003514755,0.0008444572,0.0001200335,0.00002179561,0.00003938376,0.002047411,0.0004921862,0.9954378,0.000001130084,0.0002826513,0.0006577694],"study_design_scores_gemma":[0.0006125089,0.00003348723,0.003976917,0.0003448471,0.000007723876,0.0000728839,0.0004684751,0.001377581,0.9925042,0.000009862366,0.0004642559,0.0001272422],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9954501,0.0003095406,0.000531467,0.0001412936,0.00008622011,0.00007457501,0.000002143945,0.00002200088,0.003382639],"genre_scores_gemma":[0.9994073,0.0001651897,0.0001489415,0.00002349507,0.0001469097,5.165218e-7,0.000001696265,0.00004927914,0.00005665388],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003957198,"threshold_uncertainty_score":0.4877333,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009350466059242335,"score_gpt":0.235943266219484,"score_spread":0.2265928001602417,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}