{"id":"W1925836442","doi":"10.1002/ejic.201402889","title":"NMR Spectroscopic Studies on the 1:1 Interaction of Tris(hydroxymethyl)phosphine with Cinnamic Acids","year":2014,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Molecular spectroscopy and chirality","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Phosphine; Medicinal chemistry; Hydroxymethyl; Stereochemistry; Nuclear magnetic resonance spectroscopy; Methanol; Stereospecificity; Tris; Cinnamic acid; Acetone; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008478306,0.0002546008,0.0004047312,0.00002620657,0.00009229823,0.00003126259,0.000535076,0.00004102472,0.0009023983],"category_scores_gemma":[0.0004586283,0.000158788,0.0001627738,0.00015904,0.000161758,0.00006673786,0.00008177687,0.0008089357,0.00001650572],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001192616,"about_ca_system_score_gemma":0.00005714579,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001439876,"about_ca_topic_score_gemma":5.55412e-7,"domain_scores_codex":[0.9983318,0.00012902,0.0007256322,0.0002132256,0.0003929937,0.0002073263],"domain_scores_gemma":[0.9980273,0.0001484675,0.001024482,0.0005246998,0.0001882294,0.00008679668],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002382442,0.0001170619,0.000595854,0.0001672627,0.0002689689,0.0000460117,0.0004001074,0.00005469207,0.9974875,0.0000718111,0.000316045,0.0002364492],"study_design_scores_gemma":[0.0009122558,0.0002811107,0.0003194727,0.0004241812,0.00009985161,0.000158219,0.0006562746,0.00003229248,0.9957521,0.0000923805,0.001115966,0.0001558804],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9714765,0.000369327,0.000363762,0.0005235937,0.00009995138,0.00002740354,0.000002774543,0.0000200272,0.02711669],"genre_scores_gemma":[0.9984069,0.0001165708,0.00021192,0.0001340741,0.0004442325,5.717231e-7,0.000002576137,0.00004381796,0.0006393404],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02693042,"threshold_uncertainty_score":0.9880628,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01158520408999879,"score_gpt":0.2463930779769846,"score_spread":0.2348078738869859,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}