{"id":"W1930877996","doi":"10.1139/cjc-2015-0251","title":"Systematic dismantling of a carefully designed PC<sub>carbene</sub>P pincer ligand via C–C bond activations at an iridium centre","year":2015,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Chemistry; Carbene; Decarbonylation; Phosphine; Ligand (biochemistry); Iridium; Pincer ligand; Hydrogenolysis; Medicinal chemistry; Bond cleavage; Photochemistry; Stereochemistry; Pincer movement; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001532533,0.0005505636,0.0002671444,0.0001859686,0.0002616741,0.0003063356,0.0006296769,0.0002740381,0.001181507],"category_scores_gemma":[0.0003465943,0.000237631,0.0001402058,0.0002347893,0.0003429737,0.0003716986,0.0004970562,0.0005818448,0.0003499098],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005019818,"about_ca_system_score_gemma":0.0004067724,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001043386,"about_ca_topic_score_gemma":0.002235048,"domain_scores_codex":[0.9998183,0.00002736974,0.00001279673,0.00004274047,0.00003722767,0.00006165707],"domain_scores_gemma":[0.9998614,0.00002442848,0.00004640895,0.00002365994,0.00001923422,0.00002501372],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004936427,0.00007888293,0.0003069898,0.0003428004,0.000042813,0.0003960358,0.0001450171,0.001316819,0.9808224,0.001570586,0.0003681185,0.01411598],"study_design_scores_gemma":[0.00001885872,0.0003463723,0.0003413355,0.00000506236,0.00001285658,0.0001751238,0.00001886923,0.0005599836,0.995773,0.00004555008,0.002693823,0.000009200276],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9793299,0.0008886075,0.009709846,0.0001052149,0.00004156102,0.0001899482,0.0002049183,0.0002344019,0.009295494],"genre_scores_gemma":[0.9939657,0.0003995696,0.00356523,0.00005381062,0.000006728146,0.00004488964,0.0001128619,0.00004527313,0.001806049],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001181507,"threshold_uncertainty_score":0.003952563,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01497667571650982,"score_gpt":0.2277922439371439,"score_spread":0.2128155682206341,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}