{"id":"W1935110338","doi":"10.1039/b208325f","title":"Triple C–H activation of 1,5-bis(di-tert-butylphosphino)-2-(S)-dimethylaminopentane on ruthenium gives a chiral carbene complex","year":2002,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Wilfrid Laurier University","funders":"","keywords":"Carbene; Ruthenium; Chemistry; Chelation; Medicinal chemistry; Catalysis; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001077274,0.0002228159,0.0003515549,0.0001526613,0.000186131,0.00003055921,0.001272077,0.0001699914,0.001661718],"category_scores_gemma":[0.0003012278,0.0002235777,0.0002225287,0.000717207,0.0002622563,0.0001214479,0.0003238569,0.0003868647,0.00008052503],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001423713,"about_ca_system_score_gemma":0.00002106423,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005230229,"about_ca_topic_score_gemma":0.000002527285,"domain_scores_codex":[0.9984865,0.00004487703,0.0005563486,0.0002961597,0.0003705672,0.0002455441],"domain_scores_gemma":[0.9970436,0.0003983354,0.0002955012,0.001980764,0.0001491179,0.0001326624],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003421435,0.001104823,0.0002870227,0.00004612765,0.0001633136,5.617055e-7,0.0006604781,0.00001127809,0.9779601,0.0035602,0.002595535,0.01357639],"study_design_scores_gemma":[0.0008590317,0.00001973576,0.0002289533,0.00003872614,0.00007437507,0.000003955437,0.0002689518,0.006378701,0.971506,0.0001993451,0.02015051,0.0002717132],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7454942,0.000857002,0.0002222267,0.00401481,0.00004003574,0.0002247013,0.0001797632,0.0002232222,0.2487441],"genre_scores_gemma":[0.9951565,0.000173765,0.0007593516,0.0002226928,0.00004511746,0.0000615585,0.0007937601,0.00003140239,0.002755842],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2496623,"threshold_uncertainty_score":0.9992509,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05997633020550788,"score_gpt":0.2769124989056551,"score_spread":0.2169361687001472,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}