{"id":"W1935781400","doi":"10.1039/c5cp04634c","title":"Clarifying the role of Ru in methanol oxidation at Ru<sub>core</sub>@Pt<sub>shell</sub> nanoparticles","year":2015,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Electrocatalysts for Energy Conversion","field":"Energy","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"Calgary Laboratory Services; University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; University of Calgary","keywords":"Methanol; Catalysis; Dehydrogenation; Monolayer; Nanoparticle; Adsorption; Chemistry; Rate-determining step; Ruthenium; Diffusion; Chemical engineering; Inorganic chemistry; Photochemistry; Materials science; Nanotechnology; Physical chemistry; Organic chemistry; Thermodynamics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001044312,0.000191537,0.0001874799,0.00007277227,0.0001111593,0.0001818445,0.0001960646,0.0003423597,0.0005102387],"category_scores_gemma":[0.0001872465,0.0001334969,0.0001656446,0.00005167389,0.0002268927,0.0002606222,0.0001843782,0.0002964507,0.0001783352],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001935812,"about_ca_system_score_gemma":0.00007222568,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004734665,"about_ca_topic_score_gemma":0.0005975782,"domain_scores_codex":[0.9999323,0.000006309678,0.00000458523,0.00002155936,0.00002268924,0.00001270965],"domain_scores_gemma":[0.999944,0.00001888932,0.00001196335,0.000006989736,0.00001251388,0.000005751415],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003822695,0.000006010998,0.0001369447,0.00005018482,0.000003773436,0.00004926962,0.00002547015,0.0001731417,0.9983216,0.0001219416,0.00002119284,0.001052142],"study_design_scores_gemma":[0.000003411618,0.00006425505,0.001006843,0.000002821445,0.000007572839,0.00004798861,0.00001701246,0.002324855,0.9960594,0.00003445083,0.000428858,0.00000254682],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995175,0.0005859295,0.002550879,0.00006890417,0.00001173756,0.000009581621,0.00004766998,0.00005063985,0.001499703],"genre_scores_gemma":[0.9978423,0.0001929308,0.001452384,0.00001950354,0.000003341529,0.000008945788,0.00003791938,0.00001307991,0.0004295176],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005102387,"threshold_uncertainty_score":0.001706958,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01605727047646612,"score_gpt":0.2276938407601361,"score_spread":0.21163657028367,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}