{"id":"W1944442178","doi":"10.1002/ejoc.201301100","title":"Gallium(III) Triflate Catalyzed Diastereoselective Mukaiyama Aldol Reaction by Using Low Catalyst Loadings","year":2013,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Aldol reaction; Trifluoromethanesulfonate; Chemistry; Catalysis; Triflic acid; Gallium; Organic chemistry; Lewis acid catalysis; Lewis acids and bases","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003789084,0.0008339687,0.0003830314,0.0004352068,0.0002370035,0.0002930047,0.0004034736,0.0004168866,0.001175151],"category_scores_gemma":[0.0002110343,0.0003130193,0.000463352,0.0002502073,0.0002443118,0.0005019069,0.000442908,0.0008577041,0.001117117],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001677149,"about_ca_system_score_gemma":0.000358505,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004564021,"about_ca_topic_score_gemma":0.001094996,"domain_scores_codex":[0.9997789,0.00003206003,0.00002634628,0.00003894923,0.00004745836,0.00007630072],"domain_scores_gemma":[0.9998779,0.00001789672,0.00002863673,0.00002337866,0.00002535997,0.00002682906],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004126178,0.00002139766,0.00007067638,0.0001428946,0.0000177144,0.0001832267,0.0000463629,0.0001351471,0.9947882,0.0003485433,0.0001570892,0.004047529],"study_design_scores_gemma":[0.00001040356,0.0001334782,0.0002816136,0.000006702346,0.00002643899,0.0003527734,0.00001470334,0.0004195725,0.9956964,0.0001053104,0.002934559,0.00001795816],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8151965,0.004827076,0.1631275,0.0005653441,0.0002752601,0.0002628366,0.0008199025,0.001169659,0.01375595],"genre_scores_gemma":[0.9556262,0.003235003,0.0361122,0.00008424069,0.00004390954,0.00006880057,0.000636142,0.0001201501,0.004073402],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001175151,"threshold_uncertainty_score":0.003931344,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007636858262756654,"score_gpt":0.1926155534305923,"score_spread":0.1849786951678356,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}