{"id":"W194745401","doi":"10.53846/goediss-3860","title":"Investigations into the Propagation and Termination Kinetics of the Radical Polymerization of Polar Monomers in Aqueous Solution","year":2013,"lang":"en","type":"dissertation","venue":"","topic":"Photopolymerization techniques and applications","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"École Polytechnique Fédérale de Lausanne; Queen's University; Slovenská Akadémia Vied","keywords":"Monomer; Chemistry; Arrhenius equation; Activation energy; Intermolecular force; Polymerization; Aqueous solution; Kinetics; Physical chemistry; Polymer chemistry; Molecule; Analytical Chemistry (journal); Organic chemistry; Polymer","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008328677,0.0001873845,0.0002229298,0.0001421121,0.0001097586,0.00002379063,0.000275608,0.0003017858,0.0001320697],"category_scores_gemma":[0.0001275107,0.0001333422,0.00006627524,0.0004724393,0.0002790009,0.000116608,0.00003909754,0.0002279305,7.8001e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006722051,"about_ca_system_score_gemma":0.000113556,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001452921,"about_ca_topic_score_gemma":0.0003443605,"domain_scores_codex":[0.9986213,0.00004832092,0.0006960087,0.0002370589,0.0002768302,0.0001204352],"domain_scores_gemma":[0.9986091,0.0000643806,0.0007589634,0.0003829024,0.0001469979,0.00003767344],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000006961064,0.00007361246,0.0005708864,0.0002206316,0.00001118755,2.922252e-8,0.001390979,0.0000118039,0.9809266,0.004130599,0.00004823021,0.01260848],"study_design_scores_gemma":[0.000151513,0.00001452081,0.005292636,0.0001654602,0.00004521808,0.000001291968,0.0006788257,0.004494556,0.9869483,0.001816259,0.000251808,0.0001396687],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9901534,0.0004783008,0.001886154,0.0006809923,0.0000693991,0.0008259905,0.00003806153,0.00005260795,0.005815082],"genre_scores_gemma":[0.9958795,0.0002293037,0.0006249833,0.00003499645,0.00002869995,0.0002800672,0.001005533,0.00002823341,0.001888664],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01246882,"threshold_uncertainty_score":0.5437539,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005996973154719245,"score_gpt":0.233235471885325,"score_spread":0.2272384987306058,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}