{"id":"W1947729595","doi":"10.1021/acs.joc.5b00256","title":"Stereoselective Synthesis of Chiral Sulfilimines from<i>N</i>-Mesyloxycarbamates: Metal-Nitrenes versus Metal-Nitrenoids Species","year":2015,"lang":"fr","type":"article","venue":"The Journal of Organic Chemistry","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Fonds de recherche du Québec – Nature et technologies; Université de Montréal; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation","keywords":"Chemistry; Nitrene; Amination; Rhodium; Thioether; Pyridinium; Catalysis; Yield (engineering); Ligand (biochemistry); Medicinal chemistry; Metal; Organic chemistry; Combinatorial chemistry; Stereochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001877994,0.0005014132,0.0002737942,0.0001465749,0.0001139159,0.0002297107,0.0004770622,0.0002992646,0.001122345],"category_scores_gemma":[0.000158505,0.0001839825,0.0002464226,0.0001476932,0.0001678186,0.0002640482,0.0002642197,0.0004155841,0.0005073374],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003004997,"about_ca_system_score_gemma":0.0001690541,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002577898,"about_ca_topic_score_gemma":0.0006110513,"domain_scores_codex":[0.9998785,0.00001960494,0.00001339246,0.00002528214,0.00003008966,0.00003316565],"domain_scores_gemma":[0.9999034,0.00001353803,0.00002858262,0.00001227181,0.00001819485,0.00002384383],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008187474,0.00002092924,0.000087504,0.0000861994,0.0000066302,0.0001133379,0.00004422826,0.0001340873,0.9963278,0.0004932572,0.00004591662,0.00255815],"study_design_scores_gemma":[0.000015985,0.0002452878,0.0003400673,0.000004963728,0.000008418991,0.0001515175,0.00001309906,0.0003280048,0.9958485,0.00006322034,0.002974213,0.0000066213],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9752746,0.001390666,0.01321332,0.00009172906,0.00005727801,0.0001209958,0.0003495403,0.0001886498,0.009313134],"genre_scores_gemma":[0.9874429,0.001020101,0.008285713,0.00003845456,0.00001444978,0.00005739343,0.0002766451,0.00005285102,0.002811404],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001122345,"threshold_uncertainty_score":0.003754675,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03745835328097892,"score_gpt":0.2445381862131662,"score_spread":0.2070798329321873,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}