{"id":"W1950855491","doi":"10.1002/chem.201502661","title":"Photochemical Synthesis of Complex Carbazoles: Evaluation of Electronic Effects in Both UV‐ and Visible‐Light Methods in Continuous Flow","year":2015,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":50,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Natural Sciences and Engineering Research Council of Canada; Centre in Green Chemistry and Catalysis","keywords":"Photochemistry; Carbazole; Visible spectrum; Continuous flow; Chemistry; Combinatorial chemistry; Materials science; Optoelectronics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.003251747,0.0002591465,0.0005982897,0.00008576246,0.00002685977,0.00002851676,0.0003727154,0.0001263175,0.000261658],"category_scores_gemma":[0.004614091,0.0002538413,0.0001290688,0.0002785466,0.0001961957,0.00008603335,0.00009748556,0.0009387447,0.00000203138],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004935748,"about_ca_system_score_gemma":0.0003351956,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001361676,"about_ca_topic_score_gemma":0.000001349858,"domain_scores_codex":[0.9971583,0.0004921602,0.0009304,0.000346395,0.0006363726,0.0004363294],"domain_scores_gemma":[0.9980693,0.0005654348,0.0004489542,0.0003463077,0.0002309902,0.0003390077],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001314768,0.0002378231,0.0009241903,0.0002875031,0.00005299657,0.00003457448,0.0002507484,0.0001075867,0.9894851,0.000002168508,0.0002263796,0.00825947],"study_design_scores_gemma":[0.002799402,0.00003228713,0.0007540482,0.0006431883,0.0001298274,0.0002501531,0.0002992749,0.0206993,0.9732637,0.0004338868,0.0004536524,0.0002413168],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9767647,0.0007992904,0.0002481269,0.00005001781,0.00002389852,0.0001494783,0.000008316236,0.00001808657,0.02193811],"genre_scores_gemma":[0.9959344,0.00004110989,0.003793149,0.00001275098,0.0001018092,0.00002354337,0.00000986836,0.00004549747,0.00003790985],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0219002,"threshold_uncertainty_score":0.9999914,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03145029978508701,"score_gpt":0.3212409590415964,"score_spread":0.2897906592565094,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}