{"id":"W1953751939","doi":"10.1002/poc.1908","title":"Kinetics and mechanisms of the reactions of transient silylenes with amines","year":2011,"lang":"en","type":"article","venue":"Journal of Physical Organic Chemistry","topic":"Catalysis and Oxidation Reactions","field":"Chemical Engineering","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Silylene; Reaction rate constant; Diethylamine; Amine gas treating; Triethylamine; Steric effects; Kinetics; Catalysis; Equilibrium constant; Medicinal chemistry; Photochemistry; Physical chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003676418,0.000423431,0.0002365346,0.0001490335,0.0001122362,0.0003597914,0.0003437236,0.0003404558,0.001496995],"category_scores_gemma":[0.0005417074,0.000287554,0.0003144008,0.00008278307,0.0003044699,0.0005271341,0.0001759361,0.0004493722,0.0004352657],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006641289,"about_ca_system_score_gemma":0.0001962556,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007441191,"about_ca_topic_score_gemma":0.0006463456,"domain_scores_codex":[0.9998337,0.00002264252,0.000008257268,0.00004948676,0.00004043131,0.00004550697],"domain_scores_gemma":[0.9997372,0.0001193129,0.00006799932,0.00001350861,0.0000340096,0.0000279932],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001858217,0.0000271479,0.0006508385,0.00005588857,0.00001391107,0.00005280006,0.00006485228,0.0007498217,0.9956682,0.0004255673,0.00004864206,0.002056427],"study_design_scores_gemma":[0.0000110524,0.0001826378,0.002130463,0.000003272846,0.000009177094,0.00004895465,0.00002130765,0.006492056,0.9904366,0.00009868056,0.0005556213,0.00001003906],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9916812,0.0006500914,0.006182527,0.00004636621,0.00001234929,0.00003265554,0.0001150314,0.0001097958,0.001170143],"genre_scores_gemma":[0.9966398,0.0003088469,0.001161538,0.00001758481,0.000004266426,0.00002691521,0.0001258982,0.00001526497,0.001699777],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001496995,"threshold_uncertainty_score":0.005007982,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00787889898905673,"score_gpt":0.1898420595779558,"score_spread":0.1819631605888991,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}