{"id":"W1953751939","doi":"10.1002/poc.1908","title":"Kinetics and mechanisms of the reactions of transient silylenes with amines","year":2011,"lang":"en","type":"article","venue":"Journal of Physical Organic Chemistry","topic":"Catalysis and Oxidation Reactions","field":"Chemical Engineering","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Silylene; Reaction rate constant; Diethylamine; Amine gas treating; Triethylamine; Steric effects; Kinetics; Catalysis; Equilibrium constant; Medicinal chemistry; Photochemistry; Physical chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00002561555,0.00006912492,0.0001838702,0.00001253544,0.00001401545,0.00000237787,0.00009887038,0.00003143374,0.0001116952],"category_scores_gemma":[0.00004233839,0.00004210773,0.0001031845,0.0001447813,0.00005850353,0.00004267932,0.0000171445,0.0001312885,2.124212e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001447964,"about_ca_system_score_gemma":0.00001392819,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005690884,"about_ca_topic_score_gemma":0.000001091162,"domain_scores_codex":[0.9994748,0.000003694963,0.0002468859,0.00005481142,0.000164823,0.00005495375],"domain_scores_gemma":[0.9993756,0.00004653669,0.000271551,0.0001278892,0.0001329754,0.00004540931],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001356,0.0002066432,0.00002293987,0.00006135548,0.00006564467,5.188233e-7,0.0002024595,0.00004775617,0.9989562,0.0003213626,0.000006335039,0.00009522848],"study_design_scores_gemma":[0.0002184541,0.00004290096,0.0008303261,0.00006259883,0.0001436805,0.00003856785,0.0002247043,0.0001643825,0.9978804,0.0002800558,0.00006807115,0.00004586503],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942558,0.00001836323,0.005051336,0.0000663551,0.00002131193,0.00001978888,0.000005452919,0.000004042702,0.0005575426],"genre_scores_gemma":[0.9995369,0.000006940113,0.0002474062,0.000002535538,0.00005875829,4.121371e-7,6.321208e-7,0.000008668225,0.0001377941],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005281047,"threshold_uncertainty_score":0.1717104,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00787889898905673,"score_gpt":0.1898420595779558,"score_spread":0.1819631605888991,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}