{"id":"W1958539700","doi":"10.1002/ejoc.201300850","title":"Palladium‐Catalyzed Cross‐Coupling Reaction of Functionalized Aryl‐ and Heteroarylbismuthanes with 2‐Halo(or 2‐Triflyl)azines and ‐diazines","year":2013,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Université de Montréal; Université du Québec à Montréal","keywords":"Chemistry; Palladium; Aryl; Catalysis; Reagent; Coupling reaction; Bismuth; Coupling (piping); Combinatorial chemistry; Halo; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002135092,0.000529643,0.0001941361,0.0002910608,0.0001696545,0.0001665654,0.0004444903,0.0003471889,0.001580156],"category_scores_gemma":[0.0001333578,0.0002137987,0.0002454532,0.0001683536,0.0001350314,0.0002692378,0.0003148871,0.0003750998,0.0004745631],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003227896,"about_ca_system_score_gemma":0.0002445593,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006447091,"about_ca_topic_score_gemma":0.001548377,"domain_scores_codex":[0.9998519,0.00002553185,0.000009470826,0.00002817056,0.00003553357,0.00004935908],"domain_scores_gemma":[0.9999487,0.000008027854,0.00001290512,0.000006510349,0.000009287569,0.00001455608],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006214259,0.00002851051,0.0000779627,0.00008367487,0.00002760378,0.000185238,0.00005685739,0.000334049,0.9940791,0.0008260309,0.0001359327,0.004102944],"study_design_scores_gemma":[0.000007317487,0.0001113268,0.0003237064,0.000003017623,0.00001159342,0.0001538386,0.000006256657,0.0003985972,0.99646,0.00005078916,0.002468501,0.000004936916],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9658196,0.003340099,0.01778644,0.0001473958,0.0001254828,0.00008631942,0.0002055087,0.0002707661,0.0122183],"genre_scores_gemma":[0.9880994,0.001329614,0.005500374,0.0000439412,0.00001412152,0.00003201446,0.0001698707,0.00002803408,0.004782663],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001580156,"threshold_uncertainty_score":0.005286098,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01245242605407312,"score_gpt":0.2294068974055659,"score_spread":0.2169544713514928,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}