{"id":"W1960677238","doi":"10.1039/c5dt03756e","title":"Exploring the reactivity of manganese(<scp>iii</scp>) complexes with diphenolate-diamino ligands in rac-lactide polymerization","year":2015,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"biodegradable polymer synthesis and properties","field":"Materials Science","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Methoxide; Polymerization; Monomer; Polymer chemistry; Manganese; Reactivity (psychology); Catalysis; Medicinal chemistry; Lactide; Octahedron; Crystallography; Organic chemistry; Crystal structure; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001219724,0.0002382669,0.0001289037,0.00009340307,0.00007951627,0.0002671556,0.0002223419,0.0002536734,0.0005681195],"category_scores_gemma":[0.0001935371,0.0001146129,0.0000884127,0.0001075948,0.0001272198,0.0001569633,0.000174254,0.0002004455,0.0001661213],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002524075,"about_ca_system_score_gemma":0.0000862866,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005377275,"about_ca_topic_score_gemma":0.00080619,"domain_scores_codex":[0.9999145,0.00001457038,0.000006468766,0.00001899525,0.0000219064,0.0000235231],"domain_scores_gemma":[0.9999306,0.00001597879,0.0000237808,0.000004779951,0.00001056138,0.00001415156],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008565579,0.00001082624,0.0002028845,0.00003655072,0.000004879815,0.00002921677,0.00001781564,0.0001361328,0.9985464,0.00005193131,0.00001742932,0.0008602443],"study_design_scores_gemma":[0.000006305393,0.0001169252,0.000621358,0.000002490137,0.000006013745,0.00004418076,0.000008862753,0.0006935628,0.9979771,0.00001153334,0.0005096023,0.000002075971],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.998365,0.0002336123,0.000669765,0.00001925301,0.000002572756,0.000008856598,0.00003302493,0.0000207527,0.0006472055],"genre_scores_gemma":[0.998445,0.0001583707,0.0007542945,0.00001070697,0.000001389018,0.00000852332,0.00005155591,0.000008598907,0.0005616828],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005681195,"threshold_uncertainty_score":0.001900554,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.07911200570137156,"score_gpt":0.2351993962953643,"score_spread":0.1560873905939928,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}