{"id":"W1962907671","doi":"10.1002/0471264229.os086.07","title":"Preparation of 4‐Spirocyclohexyloxazolidinone by <scp>C</scp> ‐ <scp>H</scp> Bond Nitrene Insertion","year":2009,"lang":"en","type":"other","venue":"Organic Syntheses","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal; Université de Montréal","funders":"","keywords":"Chemistry; Rhodium; Triethylamine; Nitrene; Medicinal chemistry; Potassium carbonate; Chloride; Imidazole; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000216958,0.0008249521,0.001091224,0.0003326618,0.0001470596,0.0001206978,0.0006810012,0.001143466,0.004387042],"category_scores_gemma":[0.004129244,0.0007995155,0.0003546326,0.0004027781,0.0001671831,0.0001805987,0.000105284,0.0004163316,0.0006590838],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002189805,"about_ca_system_score_gemma":0.0002152192,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003572167,"about_ca_topic_score_gemma":0.0001415059,"domain_scores_codex":[0.9966372,0.00005902016,0.0008808574,0.0009736431,0.0007921266,0.0006572097],"domain_scores_gemma":[0.9950877,0.001894702,0.001242652,0.001425977,0.000111526,0.0002373836],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000003739857,0.0004414815,0.00009404227,0.0002211997,0.0002928681,0.000005078171,0.0002499055,6.167128e-7,0.3924745,0.00004439952,0.6019396,0.004232532],"study_design_scores_gemma":[0.0001802042,0.00003658923,0.00006932443,0.0005513582,0.000282292,0.00002993399,0.0007824617,0.000006235856,0.4719132,0.00008330982,0.5259462,0.0001189549],"study_design_candidate":"not_applicable","study_design_consensus":"not_applicable","genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.05814184,0.006343655,0.0001173276,0.00005139351,0.0003474347,0.0003306582,0.0004906829,0.0006039198,0.9335731],"genre_scores_gemma":[0.2328605,0.002838675,0.000183878,0.00006919997,0.0009992109,0.00009774417,0.0005304642,0.0008083616,0.761612],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.1747186,"threshold_uncertainty_score":0.9994456,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0124730827885868,"score_gpt":0.2454261023359419,"score_spread":0.2329530195473551,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}