{"id":"W1963004378","doi":"10.1002/047084289x.rn01757","title":"Cu(Xantphos)(dmp)BF<sub>4</sub>","year":2014,"lang":"en","type":"reference-entry","venue":"Encyclopedia of Reagents for Organic Synthesis","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Dichloromethane; Chloroform; Chemistry; Tetrahydrofuran; Diethyl ether; Reagent; Acetonitrile; Phosphine; Nuclear chemistry; Methanol; Solubility; Organic chemistry; Solvent","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002068936,0.00154543,0.0009761173,0.0006765272,0.0006931135,0.0003707196,0.001745224,0.000479408,0.03695111],"category_scores_gemma":[0.0002862394,0.0005985278,0.000212623,0.00114312,0.0002782447,0.000557693,0.0004419574,0.0007009205,0.01946033],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001490312,"about_ca_system_score_gemma":0.0008851122,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00747471,"about_ca_topic_score_gemma":0.007540915,"domain_scores_codex":[0.9996661,0.00002975997,0.00001189702,0.00009205753,0.000086821,0.0001132933],"domain_scores_gemma":[0.9999235,0.00001135571,0.00001405346,0.00001196002,0.00002144732,0.00001766606],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.002727282,0.0001682675,0.0005308881,0.002153839,0.0001075986,0.0005006895,0.00007990499,0.001165078,0.8582994,0.00445517,0.07720377,0.05260814],"study_design_scores_gemma":[0.0005381088,0.0004983246,0.002666122,0.000112724,0.00006658772,0.001161769,0.00010236,0.001296025,0.7194731,0.0007045899,0.2732978,0.00008247539],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"other","genre_scores_codex":[0.5169839,0.01108001,0.08540269,0.003290985,0.002593097,0.001879667,0.04099244,0.02253418,0.315243],"genre_scores_gemma":[0.6907886,0.00971376,0.03310508,0.0008004866,0.0002735592,0.001276581,0.0364191,0.002748569,0.2248742],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.03695111,"threshold_uncertainty_score":0.1236137,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01381319269324836,"score_gpt":0.2360602261330471,"score_spread":0.2222470334397988,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}