{"id":"W1963560122","doi":"10.1039/c1cp22437a","title":"The unusual importance of activity coefficients for micelle solutions illustrated by an osmometry study of aqueous sodium decanoate and aqueous sodium decanoate + sodium chloride solutions","year":2011,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Surfactants and Colloidal Systems","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"St. Francis Xavier University","funders":"","keywords":"Chemistry; Micelle; Activity coefficient; Aqueous solution; Critical micelle concentration; Osmotic coefficient; Osmometer; Thermodynamics of micellization; Aggregation number; Sodium; Pulmonary surfactant; Thermodynamics; Inorganic chemistry; Gibbs free energy; Chromatography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004522523,0.0005012968,0.0003436348,0.0008156539,0.0002517922,0.0006851524,0.0003858366,0.00044355,0.0005653837],"category_scores_gemma":[0.001700637,0.0002445432,0.0001763983,0.0004050738,0.0006407904,0.0004639668,0.0004454708,0.0009087902,0.0002840304],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003522881,"about_ca_system_score_gemma":0.0002381669,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004425822,"about_ca_topic_score_gemma":0.0004186197,"domain_scores_codex":[0.9996983,0.00003589579,0.00003684888,0.0000674811,0.0001325229,0.00002904912],"domain_scores_gemma":[0.9989622,0.0004325157,0.0002043117,0.00006867822,0.000284549,0.0000477429],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000450767,0.000008870172,0.000958155,0.00008485287,0.000009715443,0.00009165241,0.0000506103,0.0002633837,0.9946832,0.0006005022,0.00004793624,0.003155977],"study_design_scores_gemma":[0.000004781872,0.00007108202,0.003597738,0.00001079933,0.00001782169,0.0005193778,0.0000460608,0.003562347,0.9902098,0.0004663184,0.001478536,0.00001530609],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.937769,0.006514032,0.04792685,0.0002790885,0.00009998694,0.0001421631,0.0006708342,0.0004323229,0.00616585],"genre_scores_gemma":[0.9820274,0.001959196,0.01475632,0.00004548022,0.00001544952,0.00006659713,0.00028139,0.00005892587,0.0007893614],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008156539,"threshold_uncertainty_score":0.002556086,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03724239035397593,"score_gpt":0.2575080944391988,"score_spread":0.2202657040852228,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}