{"id":"W1963628284","doi":"10.1016/j.jms.2015.02.013","title":"Fourier transform synchrotron spectroscopy of the in-plane methyl-rocking band of CD3OH","year":2015,"lang":"de","type":"article","venue":"Journal of Molecular Spectroscopy","topic":"Spectroscopy and Laser Applications","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":false,"ca_institutions":"Canadian Light Source (Canada); University of Saskatchewan; University of New Brunswick","funders":"National Research Council Canada; Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research; University of Saskatchewan","keywords":"Isotopologue; Excited state; Physics; Spectral line; Anharmonicity; Fermi resonance; Atomic physics; Fourier transform; Ground state; Molecular physics; Materials science; Nuclear magnetic resonance; Infrared; Optics; Condensed matter physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001510206,0.0001973283,0.0001345512,0.0003732115,0.0003514786,0.0001760674,0.0004804049,0.000356689,0.00460394],"category_scores_gemma":[0.0002539677,0.0001428022,0.0001115043,0.0004785125,0.0002895349,0.0002927004,0.0001817287,0.0006436537,0.0002265974],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001416236,"about_ca_system_score_gemma":0.0001467545,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001149399,"about_ca_topic_score_gemma":0.001154445,"domain_scores_codex":[0.9999176,0.00001274943,0.000003133143,0.00001610536,0.00002335528,0.00002710875],"domain_scores_gemma":[0.9997929,0.00009305576,0.00004585091,0.00001869105,0.00002928068,0.00002023997],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007844572,0.0000602899,0.001472289,0.0001024977,0.00001557404,0.0001200139,0.0001211254,0.0003018396,0.9914243,0.0004016917,0.0004492283,0.004746738],"study_design_scores_gemma":[0.00008124897,0.0002199733,0.02394268,0.00003169992,0.0000356212,0.0004534661,0.0004611669,0.006774162,0.9653839,0.0003304376,0.002262628,0.00002286604],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9946877,0.0004838973,0.001869283,0.0001603273,0.00001661551,0.000003740021,0.0002580953,0.00003737121,0.002483022],"genre_scores_gemma":[0.9971048,0.0002334487,0.001072889,0.0000466362,0.000007034061,0.000005110127,0.0003326469,0.000009323559,0.001188026],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00460394,"threshold_uncertainty_score":0.01540178,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01106582535212453,"score_gpt":0.2741785097308808,"score_spread":0.2631126843787563,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}